[Energy transfer from tryptophan to 1, N6-ethenoadenosine in frozen aqueous solution].
Mixed aggregates of tryptophan and 1, N6-ethenoadenosine (epsilon Ado) are formed in frozen aqueous solutions at 77 K. In these aggregates one observes a quenching of tryptophan fluorescence by small amounts of epsilon Ado together with a sensitized fluorescence of epsilon Ado. About 70 tryptophan molecules are able to transfer their energy to one epsilon Ado molecule.
D000241:Adenosine / Q000031:analogs & derivatives* / Q000378:metabolism; D004735:Energy Transfer; D005615:Freezing; D013050:Spectrometry, Fluorescence; D014364:Tryptophan / Q000378:metabolism*
D014364:Tryptophan; D000241:Adenosine
Transfert d'énergie du tryptophane vers la 1, N6-'ethénoadénosine en solution aqueuse congelée.