title: [Partial synthesis of adenosylcorrinoids and of 1,N6-etheno-adenosylcobalamin with a fluorescent nucleoside (author's transl].
abstract: Adenosylcobalamin and several analogs of this corrinoid are prepared by an improved method and separated by an one-step-chromatography on columns of carboxymethylcellulose. Pure water is the eluting agent. The same method is suitable for the preparation of 1,N6-ethenoadenosylcobalamin, a corrinoid with fluorescent nucleoside.
mesh_terms: D000241:Adenosine / Q000031:analogs & derivatives*; D002266:Carboxymethylcellulose Sodium; D002845:Chromatography; D005453:Fluorescence; D009705:Nucleosides; D014805:Vitamin B 12 / Q000138:chemical synthesis*
chemical_list: D009705:Nucleosides; D002266:Carboxymethylcellulose Sodium; D000241:Adenosine; D014805:Vitamin B 12
vernacular_title: Partialsynthese von Adenosyl-corrinoiden und dem 1.N6-Athen-adenosyl-cobalamin mit fluoreszierendem Nucleosidanteil