Magnetic properties and structure of oxyhemoglobin.
A review of the published evidence reinforces the conclusion reached by Pauling and Coryell in 1936 (Proc. Natl. Acad. Sci. USA 22, 210-216) that oxyhemoglobin in blood or in solution at 20 degrees has zero magnetic moment and fails to support a recent contradictory suggestion based on magnetic susceptibility of frozen samples at temperatures below 250 K. Predicted values of bond lengths and bound angles for carbonmonoxyhemoglobin and oxyhemoglobin are given.
D005615:Freezing; D007501:Iron; D008280:Magnetics; D010100:Oxygen; D010108:Oxyhemoglobins
D010108:Oxyhemoglobins; D007501:Iron; D010100:Oxygen
Proc Natl Acad Sci U S A. 1977 Feb;74(2):398-400
265510
Proc Natl Acad Sci U S A. 1977 Apr;74(4):1315-9
266173
Nature. 1964 Jul 11;203:182-3
14207238
Proc Natl Acad Sci U S A. 1936 Apr;22(4):210-6
16577697
Proc Natl Acad Sci U S A. 1975 Oct;72(10):3799-801
16578730
Proc Natl Acad Sci U S A. 1975 Nov;72(11):4200-2
16592279