N-glycosides of nitroaniline as acceptors of glucose in nonphosphorylative transglycosylation reactions.
N-glycosides of nitroaniline, D-glucose, D-mannose, D-galactose, D-ribose, D-xylose and L-arabinose were examined as acceptors of glucose in transglycosylation reactions. In the presence of these compounds, higher N-glycosides of nitroaniline were formed in the course of incubation of acid glucoamylase with maltose or glycogen. With the exception of N-glycosides of D-galactose and L-arabinose, the remaining compounds were acceptors of glucose. It follows that the acceptor properties of N-glycosides of nitroaniline are dependent on the spatial position of the hydroxyl group on the fourth carbon of the sugar moiety.
D000814:Aniline Compounds / Q000378:metabolism*; D000818:Animals; D002417:Cattle; D005087:Glucan 1,4-alpha-Glucosidase / Q000378:metabolism*; D005947:Glucose / Q000378:metabolism*; D005959:Glucosidases / Q000378:metabolism*; D006027:Glycosides / Q000378:metabolism*; D009206:Myocardium / Q000201:enzymology; D009574:Nitro Compounds / Q000378:metabolism; D013154:Spleen / Q000201:enzymology
D000814:Aniline Compounds; D006027:Glycosides; D009574:Nitro Compounds; D005959:Glucosidases; D005087:Glucan 1,4-alpha-Glucosidase; D005947:Glucose