[Use of mass spectrometry in the chemical analysis of organophosporus compounds].
The authors studied the possibility of using mass spectrometry in the chemical analysis of the biologically highly active organophosphorus compounds. The results show that methylthiophosphorous acid O-ethyl-S-(2-dimethylaminoethyl) ester has the most complex mass spectrum of all the substances under study. In the spectrum characteristic fragments were detected, having m/e values of 42, 44, 58, 71 and 72 [corresponding to the presence of the (CH3)2NCH2CH2-group], and 81, 95, 97, 105 and 125 which are characteristic of the phosphoester group. Mass spectrometric analysis, performed in this study, proved that the MS method is suitable for a qualitative analysis of biologically highly active organophosphorus compounds such as methylthiophosphorous acid O-ethyl-S-(2-dimethylaminoethyl) ester.
D055598:Chemical Phenomena; D002621:Chemistry; D007306:Insecticides / Q000032:analysis; D013058:Mass Spectrometry / Q000379:methods; D009943:Organophosphorus Compounds / Q000032:analysis*; D010573:Pesticide Residues / Q000032:analysis; D013696:Temperature
D007306:Insecticides; D009943:Organophosphorus Compounds; D010573:Pesticide Residues
Vyuzití hmotové spektrometrie pri chemické analyýze organofosforovvch sloucenin.