Structures of the homologous series of monoalkene mycolic acids from Mycobacterium smegmatis.
The positions of localization of the single carbon-carbon double bond in homologs of C series mycolic acids from Mycobacterium smegmatis have been established by 1) combined ammonia chemical ionization mass spectrometry/gas-liquid chromatography of aldehyde ozonolysis products, and 2) high resolution electron impact mass spectral analysis of vicinal glycol derivatives as their trimethylsilyl ethers. These studies have revealed that each homolog is a mixture of two isomers differing in double bond location. In each of the three homologs examined, approximately equal amounts of two isomers were present as follows: (formula: see text).
D000475:Alkenes / Q000032:analysis; D002849:Chromatography, Gas; D008401:Gas Chromatography-Mass Spectrometry; D006900:Hydroxylation; D013058:Mass Spectrometry; D009161:Mycobacterium / Q000032:analysis*; D009171:Mycolic Acids
D000475:Alkenes; D009171:Mycolic Acids