Evaluation of Amberlite XAD-2 as the extractant for carbamate insecticides from natural water.
A rapid and sensitive analytical technique to quantify carbamate insecticides at nanogram levels is reported using resin column and sorption, and desorption followed by N-P gas-liquid chromatography (GLC) analysis. The carbamates were extracted from natural water by percolation through a column of Amberlite XAD-2, followed by elution with ethyl acetate. The carbamate residues were directly analyzed by GLC with a Tracor Model 702 N-P detector. The recoveries for several carbamates including aminocarb, mexacarbate, carbaryl, propoxur, carbofuran, pirimicarb and methiocarb were from 86 to 108% at 1.0 and 0.01 ppm levels. Only 41 to 58% was recovered for methomyl. The extraction efficiency of Amberlite XAD-2 was pH-dependent as indicated in the extraction of aminocarb. More than 90% of the added aminocarb was recovered from phosphate buffer by the described method at pH 5.0 to 7.5 at 5.0 and 0.5 ppm levels.
D002219:Carbamates; D002849:Chromatography, Gas / Q000379:methods; D002852:Chromatography, Ion Exchange / Q000379:methods; D007306:Insecticides / Q000032:analysis*; D014867:Water / Q000032:analysis; D014873:Water Pollutants / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis*
D002219:Carbamates; D007306:Insecticides; D014873:Water Pollutants; D014874:Water Pollutants, Chemical; D014867:Water