Gas-liquid chromatography-mass spectrometry of thromboxane B2 and its detection in semen and human aorta by selected ion monitoring.
The gas-liquid chromatographic and mass spectrometric properties of some derivatives of thromboxane B2 methyl ester have been examined. Mass spectra were usually more informative at lower electron energies. The O-methyl- and O-n-propyloxime tri-trimethylsilyl ethers, and the tri-tert.-butyldimethylsilyl ether were used for selected ion monitoring (SIM). Thromboxane B2 was detected by SIM in bovine semen and in human aorta.
D000818:Animals; D001011:Aorta / Q000032:analysis*; D002417:Cattle; D002849:Chromatography, Gas; D002853:Chromatography, Liquid; D006801:Humans; D008297:Male; D013058:Mass Spectrometry; D012661:Semen / Q000032:analysis*; D013929:Thromboxane B2 / Q000032:analysis*; D013931:Thromboxanes / Q000032:analysis*
D013931:Thromboxanes; D013929:Thromboxane B2