[Gas chromatographic determination of biphenyl and 2-phenylphenol in the environmental air of dyeing-plant rooms of the textile industry].
A report is made on a method of sampling and analysis of biphenyl and 2-phenylphenol which are present in the environmental air of the dyeing plant rooms of the textile industry. The sampling is carried out by filtering environmental air through small pipes containing two layers of Porapak Q 80-100 mesh, the first one of 150 mg for the analysis and the other, of 50 mg, for the control, with a flux of about 1 l/min. The report includes the description of some tests concerning shifting and displacement with various fluxes, as well as the recovery of known quantities and the stability of the sampling. The saturation for the mixture of the two pollutants was about 130 mg/g of biphenyl and more than 100 mg/g of 2-phenylphenol. The gaschromatographic analysis was carried out on 2 ml of cyclohexane; methylacetate 80:20 by which was obtained the absorbent used for the sampling. An analytical column was used with 3% Apiezon L, 1% phosphoric acid, 2% Carbowax 20 M on Chromosorb W HP 80-100 mesh. These results were also confirmed by other two reference columns. This method was applied successfully to the analysis of the air of the work environment under examination.
D000395:Air Pollutants, Occupational / Q000032:analysis; D001713:Biphenyl Compounds / Q000032:analysis*; D002849:Chromatography, Gas / Q000379:methods; D004396:Coloring Agents; D005374:Filtration; D006801:Humans; D010636:Phenols / Q000032:analysis*; D013783:Textile Industry
D000395:Air Pollutants, Occupational; D001713:Biphenyl Compounds; D004396:Coloring Agents; D010636:Phenols
Determinazione gascromatografica del bifenile e del 2-fenilfenolo nell'aria ambientale delle sale tintoria dell'industria tessile.