[Transformation of tetrahydro-1,3-oxazine into 1,3,5-tris(3-hydroxypropyl)-hexahydro-1,3,5-triazine--a question of stability (author's transl)].
At room temperature tetrahydro-1,3-oxazine (THO) is converted into the very viscous 1,3,5-tris(3-hydroxypropyl)-hexahydro-1,3,5-triazine (THT) over several weeks. On heating to ca. 125 degrees C THO will be reformed from THT. The structure of THT was proven by mass-, 1H- and 13C-NMR spectra.
D055598:Chemical Phenomena; D002621:Chemistry; D004355:Drug Stability; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D010078:Oxazines; D013696:Temperature; D014227:Triazines
D010078:Oxazines; D014227:Triazines
Umwandlung des Tetrahydro-1,3-oxazins in 1,3,5-Tris(3-hydroxypropyl)-hexahydro-1,3,5-triazin--ein Stabilitätsproblem.