The structure of tridecaptin A (studies on antibiotics from the genus Bacillus. XXIV).
On examining the structure of the antibiotic tridecaptin A, the constituent amino acids were determined to be: 2,4-diaminobutyric acid(2D, 1L), Ser(1D, 1L), Glu(1L), Gly(1), Ala(1L), Val(1D, 1L), aIle(1D), Phe(1L) and Trp(1D). The constituent fatty acid was identified as beta-hydroxy anteisononanoic acid by gas chromatography and mass spectrometry. Cleavage reaction with N-bromosuccinimide, sequential analysis by EDMAN degradation, partial acid hydrolysis and some additional evidences clarified the structure of tridecaptin A.
D000595:Amino Acid Sequence; D000596:Amino Acids / Q000032:analysis; D000900:Anti-Bacterial Agents; D055598:Chemical Phenomena; D002621:Chemistry; D002849:Chromatography, Gas; D005227:Fatty Acids / Q000032:analysis; D006020:Glycopeptides; D006868:Hydrolysis; D009905:Optical Rotatory Dispersion; D010084:Oxidation-Reduction
D000596:Amino Acids; D000900:Anti-Bacterial Agents; D005227:Fatty Acids; D006020:Glycopeptides