[Effect of luminescence quenchers on the maximum concentration of radicals in proteins following UV-irradiation (77 K)].
It has been shown that the limiting number of ionization acts (z) in a protein molecule in water solution UV-irradiated at 77 K is in proportion to the molecular weight: z=8.10(-6) M. Only one ionization is possible in simple protein with M=12,5.10(4). Radicals formed after one ionization protect from the effects of UV-radiation 60--150 adjacent residues of aromatic amino acids depending on their density in protein. Presence of the acceptors of excitation energy of aromatics residues (heme, eosin) results in a sharp decrease of limiting concentration of radicals in protein.
D000596:Amino Acids; D055598:Chemical Phenomena; D002621:Chemistry; D005609:Free Radicals; D049449:Luminescence; D011506:Proteins / Q000528:radiation effects*; D014466:Ultraviolet Rays
D000596:Amino Acids; D005609:Free Radicals; D011506:Proteins
Vliianie tushiteleĭ liuminestsentsii na predel'nuiu kontsentratsiiu radikalov v belkakh pri UF-obluchenii (77 K).