Oxidative ozonolysis of 6-oxo-PGF1alpha, 11,15-diacetate, methyl acetal, methyl ester.
Ozonolysis of 6-oxo-PGF1alpha, 11,15-diacetate, methyl acetal, methyl ester followed by oxidative workup and treatment with diazomethane gave 3-acetoxy-5-hydroxy-2-(methoxycarbonyl) cyclopentane acetic acid, gamma-lactone and dimethyl 3-acetoxy-5[[-(methoxycarbonyl)valeryl]oxy]-1,2-cyclopentane dicarboxylate as two of the major products. The mass spectral properties of the latter compound were identical with those previously published by other investigators.
D055598:Chemical Phenomena; D002621:Chemistry; D002849:Chromatography, Gas; D003978:Diazomethane; D013058:Mass Spectrometry; D010084:Oxidation-Reduction; D011461:Prostaglandins F, Synthetic / Q000032:analysis
D011461:Prostaglandins F, Synthetic; D003978:Diazomethane