Synthesis of methionine carrying a chiral methyl group and its use in determining the steric course of the enzymatic C-methylation of indolepyruvate during indolmycin biosynthesis.
D000900:Anti-Bacterial Agents / Q000096:biosynthesis*; D007211:Indoles / Q000096:biosynthesis; D008715:Methionine / Q000138:chemical synthesis*; D008745:Methylation; D008780:Methyltransferases; D008956:Models, Chemical; D011773:Pyruvates
D000900:Anti-Bacterial Agents; D007211:Indoles; D011773:Pyruvates; D008715:Methionine; D008780:Methyltransferases; C001447:indolmycin