[Modeling non-enzymatic influence of membranes on the kinetics of chemical reactions].
The reduction of nitroxide radicals by rho-phenylene diamine was studied in H2O, various organic solvents in liposome suspensions and oleic acid emulsion. Some new parameters, particularly the presence of acids, appeared to effect the rate of the process. The results obtained are consistent with the hypothesis that the electron transport in coupled membranes leads to the production of undissociated acids thus supplying protons for the ATP synthesis.
D055598:Chemical Phenomena; D002621:Chemistry; D004655:Emulsions; D007700:Kinetics; D008081:Liposomes; D008956:Models, Chemical; D009829:Oleic Acids; D010084:Oxidation-Reduction; D010655:Phenylenediamines; D012997:Solvents
D004655:Emulsions; D008081:Liposomes; D009829:Oleic Acids; D010655:Phenylenediamines; D012997:Solvents
Modelirovanie nefermentnogo vliianiia membran na kinetiku khimicheskikh reaktsiĭ