Three steady state situation in an open chemical reaction system I.
In an isothermal continuously stirred tank reactor (open chemical reaction system) fed by sulphuric acid solutions of bromate, bromide and cerium (III) bistability (three steady state situation) is experimentally observed. This remarkable behavior, based on the instability of one steady state, has important consequences for the understanding of excitability and biochemical control mechanisms. The mass-balance equations for the reactor and the chemical mechanism of the reaction are combined into a simple mathematical model. The behavior of the resulting nonlinear differential equations is examined analytically and by a graphical integration procedure (method of isoclines). Using realistic kinetic data, the model shows the same behavior as observed in the experiment.
D001959:Bromates; D001965:Bromides; D001966:Bromine; D002384:Catalysis; D002563:Cerium; D055598:Chemical Phenomena; D002621:Chemistry; D007700:Kinetics; D008433:Mathematics; D008956:Models, Chemical; D013464:Sulfuric Acids; D013696:Temperature
D001959:Bromates; D001965:Bromides; D013464:Sulfuric Acids; D002563:Cerium; D001966:Bromine