Polyene antibiotics. VIII. The structure of rimocidin.
A structure is assigned to the tetraene antibiotic rimocidin, based in part on 13C NMR spectroscopy and field desorption mass spectrometry. The structure assigned revises a structure proposed in 1966 which was anomalous in relation to those of other polyene antibiotics.
D000900:Anti-Bacterial Agents; D002244:Carbon; D002264:Carboxylic Acids; D055598:Chemical Phenomena; D002621:Chemistry; D006868:Hydrolysis; D007659:Ketones; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D008958:Models, Molecular; D010084:Oxidation-Reduction; D011090:Polyenes
D000900:Anti-Bacterial Agents; D002264:Carboxylic Acids; D007659:Ketones; D011090:Polyenes; D002244:Carbon