[Breakdown of linoleic and linolenic acid hydroperoxides in the presence of ascorbic acid analysis of the volatile aldehydes (author's transl)].
Hydroperoxide emulsions with 10(-3) mol ascorbic acid were stored for 19 h at 22 degrees C. Volatile aldehydes were formed in the presence of oxygen and traces of metals. The main compounds were identified as follows (mol-%): 2-pentenal [51] and 2-hexenal [22] from 13-hydroperoxioctadeca-9,11,15-trienoic acid; propanol [38] and 2-hexenal [25] from 9-hydroperoxioctadeca-10,12,15-trienoic acid; hexanal [82] respectively [66] from 13-hydroperoxioctadeca-9,11-respectively 9-hydroperoxioctadeca-10,12-dienoic acid. C9 and C10 aldehydes were only detected in very low concentrations as fragments of the 9-hydroperoxides.
D000447:Aldehydes / Q000032:analysis*; D001205:Ascorbic Acid / Q000494:pharmacology; D008041:Linoleic Acids; D008042:Linolenic Acids; D010545:Peroxides / Q000378:metabolism*
D000447:Aldehydes; D008041:Linoleic Acids; D008042:Linolenic Acids; D010545:Peroxides; D001205:Ascorbic Acid
Abbau von Linol- und Linolensäurehydroperoxyden in Gegenwart von Ascorbinsäure