[Synthesis of 1,4-benzodiazepine and 1,5-benzodiazocine through oxidative fission of the double bond of indole derivatives].
A simplified new synthesis of some 5-phenyl-1,4-benzodiazepines and 6-phenyl-1,5-benzodiazocines, in satisfactory yields, by oxidation with sodium periodate of 1-alkylamino-2-methyl-3-phenylindoles, is described.
D001392:Azocines / Q000138:chemical synthesis*; D001569:Benzodiazepines / Q000138:chemical synthesis*; D055598:Chemical Phenomena; D002621:Chemistry; D007211:Indoles; D009682:Magnetic Resonance Spectroscopy; D010084:Oxidation-Reduction
D001392:Azocines; D007211:Indoles; D001569:Benzodiazepines
sintesi di 1,4-benzodiazepine e di 1,5-benzodiazocine per fissione ossidativa del doppio legame di derivati indolici