Epoxidation of 1,7-octadiene by Pseudomonas oleovorans: fermentation in the presence of cyclohexane.
A very efficient conversion of 1,7-octadiene to 7,8-epoxy-1-octene and 1,2-7,8-diepoxyoctane was achieved by incorporating a high concentration of cyclohexane into the conventional fermentation medium. In the presence of cyclohexane, a 90-ml% conversion of substrate to product was accomplished within 72 h, compared with an 18,5-mol% conversion in the absence of cyclohexane. Furthermore, the products were simultaneously separated and concentrated in the organic phase.
D003510:Cyclohexanes / Q000494:pharmacology*; D004852:Epoxy Compounds / Q000378:metabolism*; D004988:Ethers, Cyclic / Q000378:metabolism*; D005285:Fermentation / Q000187:drug effects; D006838:Hydrocarbons / Q000378:metabolism*; D011549:Pseudomonas / Q000378:metabolism*; D012997:Solvents
D003510:Cyclohexanes; D004852:Epoxy Compounds; D004988:Ethers, Cyclic; D006838:Hydrocarbons; D012997:Solvents