Kinetics of the substitution reaction of thiocyanate with tetrakis (3-N-methylphyridyl)porphinecobalt(III).
The equilibrium constant for the first thiocyanate addition to Co(III)-tetra(3-N-methylpyridyl)porphine is a factor of two smaller than for the less basic 4-N-methylporphine isomer. This effect is primarily due to a larger Co-SCN dissociation rate constant for the 3-isomer.
D003035:Cobalt; D007700:Kinetics; D008665:Metalloporphyrins; D013816:Thermodynamics; D013861:Thiocyanates
D008665:Metalloporphyrins; D013861:Thiocyanates; D003035:Cobalt