Derivatives of 2,3-anhydro-DL-threitol, 2,3-anhydroerythritol, 2,3:4,5-dianhydrogalactitol, and 2,3:4,5-dianhydroallitol.
alpha, omega-Disubstituted derivatives of 2,3-anhydro-DL-threitol (2), 2,3-anhydroerythritol (4), 2,3:4,5-dianhydrogalactitol (8), and 2,3:4,5-dianhydroallitol (12) have been synthesised by epoxidation of the appropriate alkeness and dienes. Benzyloxy carbonyl groups were used for protecting the primary hydroxyl groups during epoxidation.
D000477:Alkylating Agents / Q000138:chemical synthesis; D004896:Erythritol / Q000031:analogs & derivatives* / Q000138:chemical synthesis; D004988:Ethers, Cyclic / Q000138:chemical synthesis; D004376:Galactitol / Q000031:analogs & derivatives* / Q000138:chemical synthesis; D009682:Magnetic Resonance Spectroscopy; D008722:Methods; D013329:Structure-Activity Relationship; D013402:Sugar Alcohols / Q000031:analogs & derivatives* / Q000138:chemical synthesis
D000477:Alkylating Agents; D004988:Ethers, Cyclic; D013402:Sugar Alcohols; D004376:Galactitol; D004896:Erythritol