Lysergylpeptides in the course of peptide ergot alkaloid formation.
Radioactive d-lysergyl-Val-Leu-OMe, d-lysergyl-Val-Val-OMe and d-lysergyl-Val-Val-Pro-OMe were synthetized according to the dicyclohexylcarbodiimide/1-hydroxybenzotriazole procedure. These compounds are not used by intact mycelium of Claviceps as immediate precursors for cyclolalkaloid biosynthesis.
D000595:Amino Acid Sequence; D002967:Claviceps / Q000378:metabolism*; D004876:Ergot Alkaloids / Q000096:biosynthesis*; D008239:Lysine; D010452:Peptide Biosynthesis
D004876:Ergot Alkaloids; D008239:Lysine