[5-Isothiocyanato-1,8-naphthalenedicarbox-4-methylphenylimide, a new fluorescence reagent for compounds containing amino groups (author's transl)].
5-Isothiocyanato-1,3-dioxo-2-p-tolyl-2,3-dihydro-1H-benz[de]isoquinoline (= 5-isothio-cyanato-1,8-naphthalenedicarbox-4-methylphenylimide, compd.5) was synthesized from 1H,3H-naphtho(1,8-cd)pyran-1,3-dione (= 1,8-naphtha-lenedicarboxylic anhydride, compd.1) through nitration, condensation with p-toluidine, reduction with tin(II)-chloride yielding 5-amino-1,3-dioxo-2-p-tolyl-2,3-dihydro-1H-benz(de)isoquino-line (4) as intermediate, and condensation with thiophosgene. Compd. 5 can be used for qualitative and quantitative analyses of compounds containing amino groups.
D002855:Chromatography, Thin Layer; D005456:Fluorescent Dyes / Q000138:chemical synthesis*; D007094:Imides / Q000138:chemical synthesis*; D007202:Indicators and Reagents; D010084:Oxidation-Reduction
D005456:Fluorescent Dyes; D007094:Imides; D007202:Indicators and Reagents
5-Isothiocyanato-1,8-naphthalindicarbonsäure-4-methylphenylimid, ein neues Fluoreszenzreagenz für Aminogruppen-haltige Stoffe