title: 1H-N.M.R., 13C-N.M.R., and mass spectra of glucosinolates and related compounds.
abstract: The mass spectra of per(trimethylsilyl) ethers of desulfated glucosinolates are dominated by ions derived from the glucose moiety. The ions at m/e 271 and 361 are much more abundant than in the spectra shown by the corresponding derivatives of hexoses and their simple glycosides. The individual glucosinolates are distinguished by a few ions originating from their respective aglycon groups. The 1H- and 13C-n.m.r. spectra of sinigrin and some closely related compounds have been analyzed.
mesh_terms: D005947:Glucose / Q000031:analogs & derivatives*; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry
chemical_list: D005947:Glucose