Interpretation of distribution coefficients of p-alkylpyridines by a modified regular solution theory.
The hypothetical hexadecane-octane distribution coefficients for the alkylpyridines were deduced from the corresponding oil-water distribution data. The values were analyzed by a modified regular solution theory. A good correlation was noted by including the Flory-Huggins entropy factor in the calculation and by considering the deviation from the geometric mean assumption.
D055598:Chemical Phenomena; D002621:Chemistry; D006838:Hydrocarbons; D009821:Oils; D010847:Picolines; D011725:Pyridines; D012995:Solubility; D014867:Water
D006838:Hydrocarbons; D009821:Oils; D010847:Picolines; D011725:Pyridines; D014867:Water