Formation of nucleoside 5'-polyphosphates under potentially prebiological conditions.
Aqueous solutions of linear inorganic polyphosphates incubated in presence of Mg ions depolymerize to give trimetaphosphate. The presence of a nucleoside 5'-phosphate has little influence upon the reaction. Drying the products obtained by incubating a linear polyphosphate with Mg ions in the presence of a nucleoside 5'-phosphate yields nucleoside 5'-polyphosphates. The prebiological relevance of the reactions is discussed.
D055598:Chemical Phenomena; D002621:Chemistry; D002854:Chromatography, Paper; D004590:Electrophoresis, Paper; D008274:Magnesium; D010710:Phosphates; D012265:Ribonucleotides / Q000138:chemical synthesis*
D010710:Phosphates; D012265:Ribonucleotides; D008274:Magnesium