Lipid oxidation. Part 4. Products of thermooxidative polymerization of vegetable oils.
The thermal treatment of vegetable oils was studied by gel chromatography on packings of styrene-divinylbenzene copolymers. Unlike oils with a lower content of polyene acids, those with a high content of polyene acids contained a larger amount of higher oligomers of fatty acids. The gel chromatography of fatty acid methyl esters from heated oils allowed the determination of the ratio of intra- and intermolecular bonds arising by polymerization reactions. The results of determination of the iodine value of products were correlated with the data obtained by gel chromatography.
D010367:Arachis; D002850:Chromatography, Gel; D005231:Fatty Acids, Unsaturated / Q000032:analysis*; D006368:Helianthus; D006358:Hot Temperature; D009821:Oils / Q000032:analysis*; D010084:Oxidation-Reduction; D011108:Polymers; D012639:Seeds; D013025:Glycine max
D005231:Fatty Acids, Unsaturated; D009821:Oils; D011108:Polymers