title: Algebraic methods for deriving steady-state rate equations. Practical difficulties with mechanisms that contain repeated rate constants.
abstract: Methods of deriving rate equations that rely on repetition of terms for identification of redundant or invalid terms give incorrect results if used with mechanisms in which some rate constants appear more than once.
mesh_terms: D004798:Enzymes; D007554:Isotopes; D007700:Kinetics; D008433:Mathematics; D008722:Methods
chemical_list: D004798:Enzymes; D007554:Isotopes