Isolation and characterization of the photoalteration products of cis- and trans-chlordane.
Ultraviolet irradiation of cis- and trans-chlordane yielded 3 photolysis products. The expected half-caged analog of cis-chlordane was formed in high yield, and 2 minor photoproducts of trans-chlordane were observed. One of these products was a half-caged isomer. The individual photoproducts were isolated by thin layer chromatography and characterized by infrared, nuclear magnetic resonance, and mass spectrometry.
D002706:Chlordan / Q000032:analysis / Q000528:radiation effects*; D002849:Chromatography, Gas; D002855:Chromatography, Thin Layer; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D010777:Photochemistry; D010782:Photolysis; D013055:Spectrophotometry, Infrared; D014466:Ultraviolet Rays
D002706:Chlordan