[Separation of the four diastereoisomers of 6-hydroxy-5, 6-dihydrothymidine formed by gama-radiolysis of thymidine in deaerateed aqueous solution (author's transl)].
The compounds produced by gamma irradiation of deaerated aqueous solutions of thymidine have been isolated by thin-layer chromatography. The separation of (+) and (-) trans and cis diastereoisomers of thymidine "hydrates" has been carried out. Correlations between conformations given by nuclear magnetic resonance spectra and RF values are discussed.
D002855:Chromatography, Thin Layer; D012996:Solutions / Q000032:analysis; D013237:Stereoisomerism; D013936:Thymidine / Q000031:analogs & derivatives* / Q000032:analysis / Q000528:radiation effects
D012996:Solutions; D013936:Thymidine
Séparation des quatre diastéréoisoméres de l'hydroxy-6-dihydro-5,6-thymidine formés par radiolyse gamma de la thymidine en solution aqueuse désaérée