title: Physodes and the phenolic compounds of brown algae. Isolation and characterization of phloroglucinol polymers from Fucus vesiculosus (L.)
abstract: A series of vanillin-reactive compounds has been isolated from extracts of the brown alga Fucus vesiculosus. The first three members of this series have been examined by mass spectrometry, nuclear magnetic resonance spectrometry, and chemical methods, and were shown to be phloroglucinol, its phenyl-linked dimer, and a timer also composed of phloroglucinol units. Evidence is presented for the presence of tetrameric, pentameric, and hexameric phloroglucinol derivatives. Polymeric vanillin-reactive compounds were isolated and separated into two fractions. Oxidative hydrolysis of the major one produced phloroglucinol and related oligomers in low yields. The classical vanillin reactivity of physodes may thus be attributed to phloroglucinol-containing derivatives, as originally proposed by Crato (Crato, E.: Ber. Dtsch. Bot, Ges. 10, 295-302 (1892)).
mesh_terms: D002854:Chromatography, Paper; D056890:Eukaryota / Q000032:analysis*; D013058:Mass Spectrometry; D008970:Molecular Weight; D000459:Phaeophyceae / Q000032:analysis*; D010696:Phloroglucinol / Q000032:analysis*; D010860:Pigments, Biological / Q000032:analysis
chemical_list: D010860:Pigments, Biological; D010696:Phloroglucinol