title: Determination of benomyl and 2-(4-thiazolyl) benzimidazole in plant tissues by high-performance liquid chromatography using fluorimetric detection.
abstract: Methods for determining benomyl [methyl 1-(butylcarbamoyl)-2-benzimidazole carbamate] residues in plant tissues involve isolation of the residue by extraction with ethyl acetate, hydrolysis of the extracted residue to 2-aminobenzimidazole and final determination by high-performance liquid chromatography using a fluorimeter. 2-(4-Thiazolyl) benzimidazole is also determined by a similar procedure without hydrolysis. The sensitivities of these methods are 0.02 ppm for benomyl and 0.001 ppm for 2-(4-thiazolyl) benzimidazole. Recoveries of these compounds from various plant tissues were 90.5-102.9%. No interference with these methods from the plant tissues tested was found.
mesh_terms: D001542:Benomyl / Q000032:analysis*; D002219:Carbamates / Q000032:analysis*; D002851:Chromatography, High Pressure Liquid; D008722:Methods; D010573:Pesticide Residues / Q000032:analysis*; D010944:Plants / Q000032:analysis; D013050:Spectrometry, Fluorescence; D013827:Thiabendazole / Q000032:analysis*
chemical_list: D002219:Carbamates; D010573:Pesticide Residues; D013827:Thiabendazole; D001542:Benomyl