Effect of zinc ion on the interaction of some amino acid compounds of copper(II) with hydrogen peroxide.
Reaction of elemental copper and zinc powder mixtures with glycine (NH2.CH2COOH; HA) or aspartic acid (NH2CHCOOHCH2COOH; H2B) (in 1:1:2 ratio, respectively) in the presence of excess hydrogen peroxide (H2O2) at 50 degrees C, results in the formation of a new mixed metal peroxy carbonate compound corresponding to formula [Cu(Zn)2(O2(2-) (CO3)2(H2O)4], while the same reaction with elemental copper powder alone yields merely peroxy amino acid compounds having the formula [Cu(O2(2-)) (HA)2(H2O)] and [Cu(O2(2-)) (H2B) (H2O)2] for glycine and aspartic acid, respectively. These compounds have been characterized by elemental analysis, ESR, and electronic and IR spectra. It is interesting to note that both amino acids are converted to carbonate in the presence of zinc alone. A method analogous to that described above, for the reaction of elemental copper, zinc powder mixtures with succinic acid [(CH2COOH)2] or acetic acid (CH3COOH) in excess H2O2, on the other hand, gave a product essentially comprising copper succinate or acetate, respectively. These observations suggest an interesting and perhaps important phenomenon by which only the simple amino acids such as glycine and aspartic acid are converted to carbonates while their corresponding carboxylic acids form only their respective salts.
Sastry
M S
MS
Chemistry Division, Bhabha Atomic Research Centre, Bombay, India.
Gupta
S S
SS
Natarajan
V
V
Singh
A J
AJ
D001224:Aspartic Acid / Q000737:chemistry*; D002413:Cations, Divalent; D004578:Electron Spin Resonance Spectroscopy; D005998:Glycine / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
D002413:Cations, Divalent; D001224:Aspartic Acid; D006861:Hydrogen Peroxide; D015032:Zinc; D005998:Glycine