title: Syntheses of specifically deoxygenated methyl alpha-isomaltotriosides.
abstract: Specifically deoxygenated methyl alpha-isomaltotriosides were synthesized by the silver perchlorate-mediated condensation of a protected alpha-isomaltosyl chloride with suitably blocked derivatives of methyl alpha-D-glucopyranoside deoxygenated respectively at positions 2, 3, and 4, followed by deprotection.
authors.affiliation: National Institute of Diabetes, Digestive, and Kidney Diseases, National Institutes of Health, Bethesda, Maryland 20892.
authors.forename: E
authors.initials: E
authors.lastname: Petráková
authors.forename: P
authors.initials: P
authors.lastname: Kovác
authors.forename: C P
authors.initials: CP
authors.lastname: Glaudemans
mesh_terms: D002240:Carbohydrate Sequence; D006860:Hydrogen Bonding; D008969:Molecular Sequence Data; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry*; D010472:Perchlorates; D012834:Silver; D018030:Silver Compounds; D014312:Trisaccharides / Q000138:chemical synthesis*
chemical_list: D010472:Perchlorates; D018030:Silver Compounds; D014312:Trisaccharides; D012834:Silver; C078393:silver perchlorate; D010100:Oxygen