Syntheses of specifically deoxygenated methyl alpha-isomaltotriosides.
Specifically deoxygenated methyl alpha-isomaltotriosides were synthesized by the silver perchlorate-mediated condensation of a protected alpha-isomaltosyl chloride with suitably blocked derivatives of methyl alpha-D-glucopyranoside deoxygenated respectively at positions 2, 3, and 4, followed by deprotection.
Petráková
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E
National Institute of Diabetes, Digestive, and Kidney Diseases, National Institutes of Health, Bethesda, Maryland 20892.
Kovác
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P
Glaudemans
C P
CP
D002240:Carbohydrate Sequence; D006860:Hydrogen Bonding; D008969:Molecular Sequence Data; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry*; D010472:Perchlorates; D012834:Silver; D018030:Silver Compounds; D014312:Trisaccharides / Q000138:chemical synthesis*
D010472:Perchlorates; D018030:Silver Compounds; D014312:Trisaccharides; D012834:Silver; C078393:silver perchlorate; D010100:Oxygen