Quadrupole parameters of 11B in crystalline CaO.B2O3.
The quadrupole coupling constant (Qcc) and asymmetry parameter (eta) of 11B in crystalline CaO.B2O3 have been measured employing three different NQR and NMR methods: (1) 11B and 10B NQR; (2) 11B NQR and NMR; and (3) the 11B Zeeman NQR powder pattern. It is found that Qcc = 2594.3 +/- 0.5 kHz and eta = 0.515 +/- 0.001 at 77 K, and Qcc = 2573.5 +/- 0.5 kHz and eta = 0.511 +/- 0.002 at 300 K. These values are in agreement with, but far more accurate than, values obtained from a fourth procedure: measurement of the second-order quadrupolar effects evident in the m = + 1/2<-->m = - 1/2 transition of the 11B NMR spectrum.
Mao
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Department of Physics, Brown University, Providence, RI 02912.
Bray
P J
PJ
D001881:Borates / Q000737:chemistry*; D001895:Boron / Q000737:chemistry; D017610:Calcium Compounds / Q000737:chemistry*; D003460:Crystallization; D007554:Isotopes; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D015394:Molecular Structure
D001881:Borates; D017610:Calcium Compounds; D007554:Isotopes; C031316:calcium borate; D001895:Boron