Vomifoliol 9-O-beta-D-glucopyranosyl-4-O-beta-D-xylopyranosyl-6-O-beta-D- glucopyranoside: a trisaccharide glycoside from apple fruit.
From a methanolic extract of neutralized apple fruit pulp, a minor compound was isolated by adsorption chromatography on both XAD and PVPP resins followed by rotation locular countercurrent chromatography (RLCC). Clean-up for subsequent spectroscopic studies was performed by preparative HPLC on RP-18 and RP-select B phases. Data available from UV, NMR and mass spectroscopy together with the results obtained by enzymatic and acid hydrolyses revealed the structure of the polar glycoside as vomifoliol 9-O-beta-D-glucopyranosyl-4-O-beta-D-xylopyranosyl-6-O-beta-D-glucopyran oside.
Herderich
M
M
Lehrstuhl für Lebensmittelchemie, Universität Würzburg, Germany.
Feser
W
W
Schreier
P
P
D002240:Carbohydrate Sequence; D002845:Chromatography; D003512:Cyclohexanones / Q000737:chemistry / Q000302:isolation & purification*; D005638:Fruit / Q000737:chemistry*; D006027:Glycosides / Q000737:chemistry / Q000302:isolation & purification*; D006868:Hydrolysis; D008969:Molecular Sequence Data; D045792:Norisoprenoids
D003512:Cyclohexanones; D006027:Glycosides; D045792:Norisoprenoids; C074175:vomifoliol 9-O-glucopyranosyl-4-O-xylopyranosyl-6-O-glucopyranoside