1H NMR study of lithium D-lactate.
Polycrystalline D-lactic acid lithium salt [(R)-2-hydroxypropanoic acid lithium salt, lithium D-lactate] has been investigated by pulsed proton magnetic resonance methods between 77 and 300 K at 25 MHz. The main relaxation mechanism is methyl rotation; the motion is characterized by an activation energy Ea = 14.5 +/- 0.5 kJ/mol and time factor tau 0 = (1.5 +/- 0.5) x 10(-13) s. The activation energy is higher than the potential barrier obtained by ESR and ENDOR techniques for methyl rotation in the lactate radical. The methyl rotation is also responsible for a reduction of the dipolar second moment. Below 100 K the reduction of the dipolar second moment is ascribed to quantum-mechanical tunneling; an excitation energy of 6.1 +/- 1 kJ/mol is derived from a contribution to the spin-lattice relaxation times from the tunneling.
Buszko
M L
ML
Department of Physics, University of Florida, Gainesville, 32611.
Andrew
E R
ER
D003460:Crystallization; D004578:Electron Spin Resonance Spectroscopy; D007773:Lactates / Q000737:chemistry*; D019344:Lactic Acid; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008956:Models, Chemical; D015394:Molecular Structure; D013816:Thermodynamics
D007773:Lactates; D019344:Lactic Acid