Solid-state 27Al NMR studies of aluminophosphate molecular sieves. Enhanced resolution by quadrupole nutation and double-rotation.
Solid-state 27Al NMR spectra of several aluminophosphate molecular sieves have been recorded with conventional magic-angle spinning (MAS), double-rotation (DOR) and quadrupole nutation with fast MAS. Enhanced resolution was obtained in the quadrupole nutation experiment at certain radiofrequency pulse strengths. This extra resolution can be comparable to that attainable using DOR, and does not introduce spinning sidebands.
Department of Chemistry, University of Cambridge, UK.
J
J
Rocha
J
J
Klinowski
P J
PJ
Barrie
R
R
Jelinek
A
A
Pines
D000535:Aluminum / Q000737:chemistry; D017607:Aluminum Compounds / Q000737:chemistry*; D003460:Crystallization; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D015394:Molecular Structure; D010710:Phosphates / Q000737:chemistry*
D017607:Aluminum Compounds; D010710:Phosphates; D000535:Aluminum; C012714:aluminum phosphate