title: The synthesis and characterisation of 2-O-(6-O-L-glycero-alpha,beta-D-manno-heptopyranosyl-alpha-D-glucopyran osyl)-alpha,beta-D-glucopyranose.
abstract: The title compounds were synthesised, and appropriate derivatives were characterised by GLC, GLC-MS, and NMR spectroscopy. The GLC and GLC-MS data proved 2-O-(6-O-L-glycero-alpha-D-manno-heptopyranosyl-alpha-D-glucopyranosyl)- D- glucopyranose to be a constituent of the outer-core region of the lipopolysaccharide from Escherichia coli K-12, indicating the heptosyl residue to be linked to the terminal glucopyranose residue.
authors.affiliation: Institute of Organic Chemistry, Polish Academy of Sciences, Warszawa.
authors.forename: S A
authors.initials: SA
authors.lastname: Nepogodev
authors.forename: Z
authors.initials: Z
authors.lastname: Pakulski
authors.forename: A
authors.initials: A
authors.lastname: Zamojski
authors.forename: O
authors.initials: O
authors.lastname: Holst
authors.forename: H
authors.initials: H
authors.lastname: Brade
mesh_terms: D002240:Carbohydrate Sequence; D004926:Escherichia coli / Q000737:chemistry; D008070:Lipopolysaccharides / Q000138:chemical synthesis / Q000737:chemistry*; D008969:Molecular Sequence Data; D014312:Trisaccharides / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D008070:Lipopolysaccharides; D014312:Trisaccharides; C077710:2-O-(6-O-glycero-manno-heptopyranosyl-glucopyranosyl)glucopyranose