[Selective long-range DEPT NMR technique and its application to structural study of glycoside].
This paper reports a new NMR technique: selective long-range DEPT. The result obtained showed that the technique can be used to assign NMR signal of 13C, 15N and 31P nuclei, and connect the spin systems separated by quaternary carbon or heteroatom. This paper deals mainly with applying the technique for determining the glycosidation position in aglycone moiety and sequence of sugar moiety in a natural glycoside.
Miao
Z C
ZC
Academy of Military Medical Sciences, Beijing.
Feng
R
R
D006027:Glycosides / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods
D006027:Glycosides