[Biomass of Rhizopus oligosporus as an adsorbent for metal ions].
The effect of different parameters on the adsorption of metal ions by Rhizopus oligosporus has been studied. The uranium sorption by dried biomass was rapid, reaching in 5 min around 95.% of the binding capacity. The uranium-binding capacity of the culture showed an inverse relation to the growth kinetic. The relationship between sorption and equilibrium concentration was similar to an adsorption isotherm. Using the Langmuir model, a maximum sorption capacity of 0.52 mmoles uranium/g dry biomass and an affinity constant of 101 l/mmol uranium at pH 4.15 were determined. The best capacity of the biomass to bind ions (UO2(2+), Cu2+, Cd2+ and Zn2+) was best at pH 4.5-5.5. By using hydrochloric acid as eluant a 18% uranium removal of the biomass-bound ions was obtained at pH 1.0. The presence of other cations inhibited uranium-binding in the following order: Cu2+ > Cd2+ > Zn2+ > Mg2+ > Ca2+.
Castro
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Departamento de Bioquímica y Biología Molecular, Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Santiago.
Viedma
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Cotorás
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D000327:Adsorption; D002677:Chile; D003890:Desiccation; D004463:Ecology; D006863:Hydrogen-Ion Concentration; D007218:Industrial Microbiology / Q000379:methods*; D007477:Ions; D007700:Kinetics; D008670:Metals / Q000302:isolation & purification*; D008906:Mining; D012233:Rhizopus; D013696:Temperature; D014501:Uranium; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
D007477:Ions; D008670:Metals; D014874:Water Pollutants, Chemical; D014501:Uranium
Biomasa de Rhizopus oligosporus como adsorbente de iones metálicos.