A simple method for avoiding alkylthio group migration during the synthesis of thioglycoside 2,3-orthoesters. An improved synthesis of partially acylated 1-thio-alpha-L-rhamnopyranosides.
Pozsgay
V
V
Laboratory of Developmental and Molecular Immunity, National Institute of Child Health and Human Development, National Institutes of Health, Bethesda, Maryland 20892.
D000215:Acylation; D002236:Carbohydrate Conformation; D004952:Esters; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D012210:Rhamnose / Q000031:analogs & derivatives*; D013865:Thioglycosides / Q000138:chemical synthesis*
D004952:Esters; D007202:Indicators and Reagents; D013865:Thioglycosides; D012210:Rhamnose