A new fumonisin from solid cultures of Fusarium moniliforme.
A new fumonisin has been isolated from Fusarium moniliforme isolate MRC826 grown on corn. It was shown by NMR and mass spectrometry to be an isomer of fumonisin B2 that has free hydroxyl groups at C-3 and C-10 instead of the normal C-3 and C-5. This new fumonisin was detected in cultures of most isolates of F. moniliforme that were examined and was usually present at concentrations similar to those of fumonisin B2. Two isolates of F. moniliforme that produce significantly higher levels of this new isomer were identified.
Plattner
R D
RD
Bioactive Constituents Research Unit, USDA/ARS, Peoria, IL 61604.
Weisleder
D
D
Shackelford
D D
DD
Peterson
R P
RP
Powell
R G
RG
D002855:Chromatography, Thin Layer; D037341:Fumonisins; D008401:Gas Chromatography-Mass Spectrometry; D006863:Hydrogen-Ion Concentration; D006868:Hydrolysis; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D009183:Mycotoxins / Q000737:chemistry / Q000302:isolation & purification*
D037341:Fumonisins; D009183:Mycotoxins; C056934:fumonisin B2