A novel photoadduct of 4,5',8-trimethylpsoralen and adenosine.
A novel photoadduct of 4,5',8-trimethylpsoralen (TMP) and adenosine was isolated and purified by reverse-phase liquid chromatography. The structure of the photoproduct was determined by various spectral methods and found to be a TMP-adenosine 1:1 adduct resulting from the covalent bond formation between the carbon C(4) of TMP and ribose 4'-carbon of adenosine.
Yun
M H
MH
Department of Chemistry, Korea Advanced Institute of Science and Technology, Seoul.
Choi
S J
SJ
Shim
S C
SC
D000241:Adenosine / Q000737:chemistry / Q000528:radiation effects*; D015394:Molecular Structure; D010777:Photochemistry; D011838:Radiation-Sensitizing Agents / Q000138:chemical synthesis / Q000737:chemistry; D014307:Trioxsalen / Q000138:chemical synthesis / Q000737:chemistry / Q000528:radiation effects*
D011838:Radiation-Sensitizing Agents; D000241:Adenosine; D014307:Trioxsalen