Quantitative treatments of protonation equilibria shifts in micellar systems.
The paper reviews the theoretical models and equations used for the interpretation of weak acid dissociation equilibria in the presence of micellar systems. The models and the equations of the literature can be rewritten and reinterpreted in terms of the generalized pseudophase model, for which the basic equations are reported. Some new relationships for the titration of weak acids in micellar systems are presented.
Minero
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Dipartimento di Chimica Analitica, Università di Torino, Italy.
Pelizzetti
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D006863:Hydrogen-Ion Concentration; D008433:Mathematics; D008823:Micelles; D008958:Models, Molecular; D009994:Osmolar Concentration
D008823:Micelles