[Reactions of 1-(X-benzoyl)-4-R-thiosemicarbazide with chloroacetone and omega-bromoacetophenone. II. 4-Phenyl- and 4-(p-tolyl)-thiosemicarbazide of p-nitrobenzoic acid].
The reactions of 4-phenyl- and 4-(p-tolyl)-thiosemicarbazide of p-nitrobenzoic acid (Ic, d) with chloroacetone and omega-bromoacetophenone were investigated in: 1) methanolic medium (method D); 2) methanolic medium in the presence of anhydrous CH3COONa (method E); 3) methanolic medium in the presence of N(C2H5)3 (method F). The properties of compounds IIe-h and IIIe-h were determined under the conditions of basic and acidic hydrolysis. The results of UV and IR spectroscopic measurements were reported.
Bielak
E
E
Katedra i Zakład Chemii Ogólnej, Akademia Medyczna w Lublinie.
Biliński
S
S
D000096:Acetone / Q000031:analogs & derivatives* / Q000737:chemistry; D000098:Acetophenones / Q000737:chemistry*; D006868:Hydrolysis; D009579:Nitrobenzoates / Q000737:chemistry*; D012663:Semicarbazides / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet
D000098:Acetophenones; D009579:Nitrobenzoates; D012663:Semicarbazides; D000096:Acetone; C005151:thiosemicarbazide; C006973:chloroacetone; C013190:phenacyl bromide; C008629:4-nitrobenzoic acid
Reakcje 1-(X-benzoilo)-4-R-tiosemikarbazydu z chloroacetonem i omega-bromoacetofenonem. II. 4-Fenylo- i 4-(p-tolio)-tiosemikarbazyd kwasu p-nitrobenzoesowego.