title: [Reactions of 1-(X-benzoyl)-4-R-thiosemicarbazide with chloroacetone and omega-bromoacetophenone. I. 4-Phenyl- and 4-(p-tolyl)-thiosemicarbazide of p=chlorobenzoic acid].
abstract: The reactions of 4-phenyl- and 4-(p-tolyl)-thiosemicarbazide of p-chlorobenzoic acid (Ia, b) with chloroacetone and omega-bromoacetophenone were investigated in: 1) methanolic medium (method D); 2) methanolic medium in the presence of anhydrous CH3COONa (method E); 3) methanolic medium in the presence of N(C2H5)3 (method F). The properties of compounds IIa-d and IIIa-d were determined under the conditions of basic and acidic hydrolysis. The results of UV and IR spectroscopic measurements were reported.
authors.affiliation: Katedra i Zakład Chemii Ogólnej, Akademia Medyczna w Lublinie.
authors.forename: E
authors.initials: E
authors.lastname: Bielak
authors.forename: S
authors.initials: S
authors.lastname: Biliński
mesh_terms: D000096:Acetone / Q000031:analogs & derivatives* / Q000737:chemistry; D000098:Acetophenones / Q000737:chemistry*; D002723:Chlorobenzoates / Q000737:chemistry*; D006868:Hydrolysis; D012663:Semicarbazides / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet
chemical_list: D000098:Acetophenones; D002723:Chlorobenzoates; D012663:Semicarbazides; D000096:Acetone; C005151:thiosemicarbazide; C006973:chloroacetone; C013190:phenacyl bromide; C040768:4-chlorobenzoic acid
vernacular_title: Reakcje 1-(X-benzoilo)-4-R-tiosemikarbazydu z chloroacetonem i omega-bromoacetofenonem. I. 4-Fenylo- i 4-(p-tolilo)-tiosemikarbazyd kwasu p-chlorobenzoesowego.