Ruthenium red complexation with ionic polysaccharides in dilute aqueous solutions: chirooptical evidence of stereospecific interaction.
This paper presents optical and chirooptical data on the interaction of the microscopy-staining agent ruthenium red with carboxylated polysaccharides in dilute aqueous solution. The polysaccharides used are both natural (alginate and pectate) and semisynthetic (C6-oxidized cellulose and C6-oxidized amylose). A preliminary discussion of the molecular structure and conformational features which control the interaction is presented.
Dipartimento di Biochimica, Biofisica e Chimica delle Macromolecole, Università di Trieste, Italy.
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D000464:Alginates; D000688:Amylose; D002482:Cellulose; D055598:Chemical Phenomena; D002621:Chemistry; D002942:Circular Dichroism; D010368:Pectins; D011134:Polysaccharides; D012428:Ruthenium; D012430:Ruthenium Red; D013057:Spectrum Analysis; D013237:Stereoisomerism
D000464:Alginates; D011134:Polysaccharides; D012430:Ruthenium Red; D012428:Ruthenium; D010368:Pectins; D002482:Cellulose; D000688:Amylose; C003181:polygalacturonic acid