title: [Phosphorylated derivitaves of All-Z and 3-demethyl-tri-TRANS, di-cis- hexaprenols as substrates for O-antigen polysaccharide biosynthesis in Salmonella anatum].
abstract: Phosphates of all-Z- and 3-demethyl-tri-trans, di-cis-hexaprenols have been prepared and studied as substrates for enzymes of the Salmonella anatum O-specific polysaccharide biosynthesis. Methyl group in alpha-isoprenic unit proved to be essential for the enzyme-substrate interaction, whereas the presence of E-isoprenic units near the omega-end of the polyprenol is not significant.
authors.forename: N A
authors.initials: NA
authors.lastname: Kalinchuk
authors.forename: L L
authors.initials: LL
authors.lastname: Danilov
authors.forename: T N
authors.initials: TN
authors.lastname: Druzhinina
authors.forename: S D
authors.initials: SD
authors.lastname: Mal'tsev
authors.forename: V N
authors.initials: VN
authors.lastname: Shibaev
authors.forename: O N
authors.initials: ON
authors.lastname: Iudina
authors.forename: N Ia
authors.initials: NIa
authors.lastname: Grigor'eva
authors.forename: A M
authors.initials: AM
authors.lastname: Moiseenkov
mesh_terms: D000942:Antigens, Bacterial / Q000096:biosynthesis*; D008070:Lipopolysaccharides / Q000096:biosynthesis*; D019081:O Antigens; D010766:Phosphorylation; D012475:Salmonella / Q000201:enzymology / Q000378:metabolism*; D013237:Stereoisomerism; D013379:Substrate Specificity; D013729:Terpenes / Q000737:chemistry*
chemical_list: D000942:Antigens, Bacterial; D008070:Lipopolysaccharides; D019081:O Antigens; D013729:Terpenes
vernacular_title: Fosforilirovannye proizvodnye polnost'iu-Z- i 3-desmetil-tri-trans, di-tsis-geksaprenolov kak substraty fermentov biosinteza O-antigennogo polisakharida Salmonella anatum.