[Trityl-cyanoethylidene condensation of azidosaccharide derivatives as a route to hexosaminoglycans. Synthesis of the O-antigenic polysaccharide of Pseudomonas aeruginosa X (Meitert)].
Derivatives of azidosugars were shown to be stable under conditions of trityl-cyanoethylidene condensation. Tritylated 1,2-O-(1-cyano)ethylidene derivative of 2-azido-2-deoxy-beta-D-mannopyranosyl-(1----4)-L-rhamnopyranose was used as a starting material for the synthesis of [----3)-beta-D-ManNAc-(1----4)-alpha-L-Rha-(1----]n, the O-specific polysaccharide of Pseudomonas aeruginosa X (Meitert).
Tsvetkov
Iu E
IuE
Bakinovskiĭ
L V
LV
Kochetkov
N K
NK
D001386:Azides / Q000737:chemistry*; D004187:Disaccharides / Q000737:chemistry*; D005030:Ethylenes / Q000737:chemistry*; D006025:Glycosaminoglycans / Q000138:chemical synthesis*; D019081:O Antigens; D011135:Polysaccharides, Bacterial; D011550:Pseudomonas aeruginosa / Q000276:immunology*
D001386:Azides; D004187:Disaccharides; D005030:Ethylenes; D006025:Glycosaminoglycans; D019081:O Antigens; D011135:Polysaccharides, Bacterial; C016489:hexosaminoglycans; C074256:2-azido-2-deoxymannopyranosyl-(1,4)-rhamnopyranose
Tritil-tsianoétilidenovaia kondensatsiia proizvodnykh azidosakharov kak put' k geksozaminoglikanam. Sintez O-antigennogo polisakharida Pseudomonas aeruginosa X (Meĭtert).