title: Attenuation of 4-I-phenol-enhanced chemiluminescence by non-enhancer phenols.
abstract: The intensity of 4-I-phenol-enhanced chemiluminescence from the luminol-H2O2-horseradish peroxidase system is markedly attenuated in the presence of low concentrations of non-enhancer phenols. Under the conditions studied, the effect is not associated with competition between 4-I-phenol and non-enhancer phenol for the enzyme intermediates, Compounds I and II, but involves a competition between non-enhancer phenol and luminol most probably for the 4-I-phenoxy radical.
authors.affiliation: Department of Chemistry, University of Newcastle upon Tyne, UK.
authors.forename: T E
authors.initials: TE
authors.lastname: Candy
authors.forename: P
authors.initials: P
authors.lastname: Jones
mesh_terms: D003408:Cresols / Q000378:metabolism; D006735:Horseradish Peroxidase / Q000378:metabolism; D006861:Hydrogen Peroxide / Q000378:metabolism; D007462:Iodobenzenes / Q000737:chemistry* / Q000378:metabolism; D007700:Kinetics; D008163:Luminescent Measurements; D008165:Luminol / Q000378:metabolism; D013268:Stimulation, Chemical
chemical_list: D003408:Cresols; D007462:Iodobenzenes; C032538:4-cresol; C050181:4-iodophenol; D008165:Luminol; D006861:Hydrogen Peroxide; D006735:Horseradish Peroxidase