title: Synthesis of the nucleoside analogues of 3-deoxy-D-glycero-D-galacto-2-nonulosonic acid (KDN).
abstract: Several mono- and di-saccharide nucleoside analogues of 3-deoxy-D-glycero-D-galacto-2-nonulosonic acid (KDN, 1) were synthesized under Vorbrüggen, Williamson and Koenigs-Knorr reaction conditions. The stereochemistry at the anomeric position of these compounds were elucidated by means of NMR and acid catalyzed hydrolysis.
authors.affiliation: School of Pharmaceutical Sciences, Kitasato University, Tokyo, Japan.
authors.forename: M
authors.initials: M
authors.lastname: Nakamura
authors.forename: S
authors.initials: S
authors.lastname: Fujita
authors.forename: K
authors.initials: K
authors.lastname: Furuhata
authors.forename: H
authors.initials: H
authors.lastname: Ogura
mesh_terms: D002240:Carbohydrate Sequence; D008969:Molecular Sequence Data; D015394:Molecular Structure; D009705:Nucleosides / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D013400:Sugar Acids / Q000737:chemistry*
chemical_list: D009705:Nucleosides; D013400:Sugar Acids; C050008:3-deoxyglycero-galacto-nonulosonic acid