Synthesis and properties of oligonucleotide derivative with P(V) porphyrin.
Oligonucleotide derivatives with a P(V)tetraphenylporphyrin at the internucleotidic phosphodiester linkage were synthesized. Their interactions with the complementary oligonucleotide and pyrene-labeled oligonucleotide were investigated. Fluorescence from the porphyrin moiety was strongly quenched by the addition of the pyrene-labeled oligonucleotide and the template oligonucleotide.
Kitamura
M
M
Division of Molecular Engineering, Graduate School of Engineering, Kyoto University, Japan.
Nimura
A
A
Kunimoto
K
K
Segawa
H
H
Shimidzu
T
T
D001483:Base Sequence; D008969:Molecular Sequence Data; D015394:Molecular Structure; D009838:Oligodeoxyribonucleotides / Q000138:chemical synthesis* / Q000737:chemistry; D011166:Porphyrins / Q000737:chemistry*; D011721:Pyrenes / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet
D009838:Oligodeoxyribonucleotides; D011166:Porphyrins; D011721:Pyrenes