title: Condensation reactions between 2-phenylthio-2,3-dideoxyribose derivatives and nucleic bases.
abstract: The effects of phenylthio group at C-2 of 2,3-dideoxyribose were examined for the stereoselectivities in condensation reactions between sugars and pyrimidine bases. In the case of mono-PhS sugar, the 1,2-trans-anomers were mainly obtained in the ratio of 9:1. Condensation reactions with di-PhS-sugar gave the anomeric mixtures of alpha:beta = 2:8.
authors.affiliation: Life Science Research Laboratory, Japan Tobacco Inc., Kanagawa.
authors.forename: H
authors.initials: H
authors.lastname: Kawakami
authors.forename: T
authors.initials: T
authors.lastname: Ebata
authors.forename: K
authors.initials: K
authors.lastname: Koseki
authors.forename: K
authors.initials: K
authors.lastname: Matsumoto
authors.forename: H
authors.initials: H
authors.lastname: Matsushita
mesh_terms: D002241:Carbohydrates / Q000737:chemistry; D003855:Deoxyribose / Q000737:chemistry*; D015394:Molecular Structure; D011743:Pyrimidines / Q000737:chemistry
chemical_list: D002241:Carbohydrates; D011743:Pyrimidines; D003855:Deoxyribose