title: Synthesis and properties of oligonucleotide derivative with P(V) porphyrin.
abstract: Oligonucleotide derivatives with a P(V)tetraphenylporphyrin at the internucleotidic phosphodiester linkage were synthesized. Their interactions with the complementary oligonucleotide and pyrene-labeled oligonucleotide were investigated. Fluorescence from the porphyrin moiety was strongly quenched by the addition of the pyrene-labeled oligonucleotide and the template oligonucleotide.
authors.affiliation: Division of Molecular Engineering, Graduate School of Engineering, Kyoto University, Japan.
authors.forename: M
authors.initials: M
authors.lastname: Kitamura
authors.forename: A
authors.initials: A
authors.lastname: Nimura
authors.forename: K
authors.initials: K
authors.lastname: Kunimoto
authors.forename: H
authors.initials: H
authors.lastname: Segawa
authors.forename: T
authors.initials: T
authors.lastname: Shimidzu
mesh_terms: D001483:Base Sequence; D008969:Molecular Sequence Data; D015394:Molecular Structure; D009838:Oligodeoxyribonucleotides / Q000138:chemical synthesis* / Q000737:chemistry; D011166:Porphyrins / Q000737:chemistry*; D011721:Pyrenes / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet
chemical_list: D009838:Oligodeoxyribonucleotides; D011166:Porphyrins; D011721:Pyrenes