Comparison of microwave digestion with conventional wet ashing and dry ashing digestion for analysis of lead, cadmium, chromium, copper, and zinc in shellfish by flame atomic absorption spectroscopy.
A closed vessel microwave digestion procedure was developed for shellfish samples. This procedure was compared with wet and dry ash procedures for levels of lead, cadmium, chromium, copper, and zinc. Results obtained for microwave and conventional wet ash digestion were comparable. The dry ashing procedure produced results consistently lower than either of the other methods. Recoveries ranged from 80-92% for microwave and wet ashing procedures and 54-72% for the dry ashing procedure. Accuracy was also determined by analyzing lobster hepatopancreas marine reference material. Values for Pb, Cd, and Cr fell within the range specified for the reference material for all 3 digestion procedures; however, values were lower for Cu and Zn. Results of this study show that microwave digestion is comparable to wet ashing.
McCarthy
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Rhode Island Department of Health Laboratories, Providence 02904.
Ellis
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D000818:Animals; D049872:Bivalvia / Q000032:analysis; D002104:Cadmium / Q000032:analysis; D002857:Chromium / Q000032:analysis; D003300:Copper / Q000032:analysis; D007202:Indicators and Reagents; D007854:Lead / Q000032:analysis; D008099:Liver / Q000737:chemistry; D008670:Metals / Q000032:analysis*; D008872:Microwaves; D008121:Nephropidae / Q000032:analysis; D010179:Pancreas / Q000737:chemistry; D012758:Shellfish / Q000032:analysis*; D013054:Spectrophotometry, Atomic; D015032:Zinc / Q000032:analysis
D007202:Indicators and Reagents; D008670:Metals; D002104:Cadmium; D002857:Chromium; D007854:Lead; D003300:Copper; D015032:Zinc