Vibrational Raman optical activity of carbohydrates.
Vibrational Raman optical activity (R.o.a.) spectra of a range of carbohydrates in aqueous solution, measured in back-scattering between 700 and 1500 cm-1, are presented. Features were revealed that appear to be characteristic of details of the stereochemistry. Effects associated with the glycosidic linkage in di- and oligo-saccharides are prominent.
Barron
L D
LD
Chemistry Department, The University, Glasgow, Great Britain.
Gargaro
A R
AR
Wen
Z Q
ZQ
D001089:Arabinose / Q000737:chemistry; D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D002241:Carbohydrates / Q000737:chemistry*; D002475:Cellobiose / Q000737:chemistry; D003505:Cyclodextrins / Q000737:chemistry; D005947:Glucose / Q000031:analogs & derivatives / Q000737:chemistry; D008320:Maltose / Q000737:chemistry; D008969:Molecular Sequence Data; D010429:Pentoses / Q000737:chemistry; D013059:Spectrum Analysis, Raman; D014312:Trisaccharides / Q000737:chemistry; D014732:Vibration; D014994:Xylose / Q000737:chemistry; D047391:alpha-Cyclodextrins
D002241:Carbohydrates; D003505:Cyclodextrins; D010429:Pentoses; D014312:Trisaccharides; D047391:alpha-Cyclodextrins; D002475:Cellobiose; C014989:1,6-anhydro-beta-glucopyranose; C008317:maltotriose; C043333:lyxose; D008320:Maltose; D014994:Xylose; D001089:Arabinose; D005947:Glucose; C032613:alpha-cyclodextrin