Rapid pentachlorophenol evaluation in solid matrixes by second derivative UV spectroscopy for application to wood and leather samples.
A method for the quail-quantitative evaluation of pentachlorophenol (PCP) in solid matrixes has been developed. The procedure is based on solid-liquid extraction of solid samples (leather or wood), followed by purification on a cyanopropyl column and determination of the preservative by second derivative UV spectroscopy considering the PCP A peak-through value (304-297 nm). The method allows rapid PCP determination in the concentration range 1-40 micrograms/mL; any matrix interference is avoided by the purification step and recoveries of the preservative were 99.12% (RSD% 0.13) for the leather matrix and 98.03 (RSD% 0.17) for the wood matrix.
Secchieri
M
M
Università di Padova, Dipartimento di Scienze Farmaceutiche, Italy.
Benassi
C A
CA
Pastore
S
S
Semenzato
A
A
Bettero
A
A
Levorato
M
M
Guerrato
A
A
D008832:Microchemistry / Q000379:methods; D010416:Pentachlorophenol / Q000032:analysis*; D013056:Spectrophotometry, Ultraviolet / Q000379:methods; D013057:Spectrum Analysis / Q000379:methods; D013633:Tanning; D014934:Wood
D010416:Pentachlorophenol