[Application of 2D-NMR techniques in the structure determination of hypodematine].
A novel alkaloid, named hypodematine, was isolated from Hypodematium sinense Iwatsuki (belonging to the lypterdaceae). Its structure has been elucidated to have a novel skeleton of benzo-aza-cyclooctatetraene with a phenyl substitution by means of the 1H-1H COSY, 1H-13C COSY and long-range 1H-13C COSY spectroscopy.
Chen
Y M
YM
Jining Medical College.
Lu
Y H
YH
Chen
Y J
YJ
Ma
C S
CS
Yu
D Q
DQ
D000470:Alkaloids / Q000737:chemistry* / Q000302:isolation & purification; D004365:Drugs, Chinese Herbal / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy
D000470:Alkaloids; D004365:Drugs, Chinese Herbal; C071427:hypodematine