Synthesis of the sodium salts of methyl 2-O-alpha-L-fucopyranosyl-alpha-L-fucopyranoside 3- and 4-sulfate.
Synthesis of methyl 2-O-alpha-L-fucopyranosyl-alpha-L-fucopyranoside 3- and 4-sulfate was accomplished through the use of a key glycosyl donor, methyl 2,3,4-tri-O-benzyl-1-thio-beta-L-fucopyranoside, with methyl 2,3-O-isopropylidene-alpha-L-fucopyranoside and methyl 4-O-acetyl-3-O-benzyl-alpha-fucopyranoside as acceptors.
Jain
R K
RK
Department of Gynecologic Oncology, Roswell Park Memorial Institute, New York State Department of Health, Buffalo 14263.
Matta
K L
KL
D002240:Carbohydrate Sequence; D002247:Carbon Isotopes; D004187:Disaccharides / Q000138:chemical synthesis*; D006031:Glycosylation; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008759:Methylglycosides / Q000138:chemical synthesis*; D008969:Molecular Sequence Data; D015394:Molecular Structure; D011522:Protons
D002247:Carbon Isotopes; D004187:Disaccharides; D008759:Methylglycosides; D011522:Protons; C068273:methyl 2-O-fucopyranosylfucopyranoside 3 sulfate; C068274:methyl-2-O-fucopyranosylfucopyranoside 4-sulfate