title: Estimation of vulnerable zones due to accidental release of toxic materials resulting in dense gas clouds.
abstract: Heavy gas dispersion models have been developed at IIT (hereinafter referred as IIT heavy gas models I and II) with a view to estimate vulnerable zones due to accidental (both instantaneous and continuous, respectively) release of dense toxic material in the atmosphere. The results obtained from IIT heavy gas models have been compared with those obtained from the DEGADIS model [Dense Gas Dispersion Model, developed by Havens and Spicer (1985) for the U.S. Coast Guard] as well as with the observed data collected during the Burro Series, Maplin Sands, and Thorney Island field trials. Both of these models include relevant features of dense gas dispersion, viz., gravity slumping, air entrainment, cloud heating, and transition to the passive phase, etc. The DEGADIS model has been considered for comparing the performance of IIT heavy gas models in this study because it incorporates most of the physical processes of dense gas dispersion in an elaborate manner, and has also been satisfactorily tested against field observations. The predictions from IIT heavy gas models indicate a fairly similar trend to the observed values from Thorney Island, Burro Series, and Maplin experiments with a tendency toward overprediction. There is a good agreement between the prediction of IIT Heavy Gas models I and II with those from DEGADIS, except for the simulations of IIT heavy gas model-I pertaining to very large release quantities under highly stable atmospheric conditions. In summary, the performance of IIT heavy gas models have been found to be reasonably good both with respect to the limited field data available and various simulations (selected on the basis of relevant storages in the industries and prevalent meteorological conditions performed with DEGADIS). However, there is a scope of improvement in the IIT heavy gas models (viz., better formulation for entrainment, modification of coefficients, transition criteria, etc.). Further, isotons (nomograms) have been prepared by using IIT heavy gas models for chlorine, which provide safe distance for various storage amounts for 24 meteorological scenarios prevalent in the entire year. These nomograms are prepared such that a nonspecialist can use them easily for control and management in case of an emergency requiring the evacuation of people in the affected region. These results can also be useful for siting and limiting the storage quantities.
authors.affiliation: Centre for Atmospheric Sciences, Indian Institute of Technology, New Dehli.
authors.forename: M P
authors.initials: MP
authors.lastname: Singh
authors.forename: M
authors.initials: M
authors.lastname: Mohan
authors.forename: T S
authors.initials: TS
authors.lastname: Panwar
authors.forename: H V
authors.initials: HV
authors.lastname: Chopra
mesh_terms: D000062:Accidents, Occupational; D000395:Air Pollutants, Occupational / Q000032:analysis*; D002713:Chlorine / Q000032:analysis*; D004189:Disaster Planning; D004630:Emergencies; D005740:Gases / Q000032:analysis*; D015386:Hazardous Substances / Q000032:analysis*; D008452:Maximum Allowable Concentration; D008962:Models, Theoretical; D012307:Risk Factors; D012621:Seasons; D014887:Weather
chemical_list: D000395:Air Pollutants, Occupational; D005740:Gases; D015386:Hazardous Substances; D002713:Chlorine