title: Synthesis of the sodium salts of methyl 2-O-alpha-L-fucopyranosyl-alpha-L-fucopyranoside 3- and 4-sulfate.
abstract: Synthesis of methyl 2-O-alpha-L-fucopyranosyl-alpha-L-fucopyranoside 3- and 4-sulfate was accomplished through the use of a key glycosyl donor, methyl 2,3,4-tri-O-benzyl-1-thio-beta-L-fucopyranoside, with methyl 2,3-O-isopropylidene-alpha-L-fucopyranoside and methyl 4-O-acetyl-3-O-benzyl-alpha-fucopyranoside as acceptors.
authors.affiliation: Department of Gynecologic Oncology, Roswell Park Memorial Institute, New York State Department of Health, Buffalo 14263.
authors.forename: R K
authors.initials: RK
authors.lastname: Jain
authors.forename: K L
authors.initials: KL
authors.lastname: Matta
mesh_terms: D002240:Carbohydrate Sequence; D002247:Carbon Isotopes; D004187:Disaccharides / Q000138:chemical synthesis*; D006031:Glycosylation; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008759:Methylglycosides / Q000138:chemical synthesis*; D008969:Molecular Sequence Data; D015394:Molecular Structure; D011522:Protons
chemical_list: D002247:Carbon Isotopes; D004187:Disaccharides; D008759:Methylglycosides; D011522:Protons; C068273:methyl 2-O-fucopyranosylfucopyranoside 3 sulfate; C068274:methyl-2-O-fucopyranosylfucopyranoside 4-sulfate