Dithyreanitrile: an unusual insect antifeedant from Dithyrea wislizenii.
Dithyreanitrile, a novel sulfur-containing indole alkaloid, was isolated from the seeds of Dithyrea wislizenii (Cruciferae). Dithyreanitrile inhibits feeding of fall armyworm (Spodoptera frugiperda) and European corn borer (Ostrinia nubilalis) larvae. Dithyreanitrile, the first natural product with two sulfur atoms and a nitrile attached to the same carbon, was characterized by X-ray diffraction, spectroscopy, and chemical synthesis.
Powell
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RG
USDA/ARS Northern Regional Research Center, Peoria, Illinois 61604.
Mikolajczak
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Zilkowski
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BW
Lu
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Mantus
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Clardy
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D000470:Alkaloids / Q000302:isolation & purification / Q000633:toxicity*; D000818:Animals; D005247:Feeding Behavior / Q000187:drug effects*; D007313:Insecta / Q000187:drug effects*; D009682:Magnetic Resonance Spectroscopy; D012639:Seeds; D014961:X-Ray Diffraction
D000470:Alkaloids; C068130:dithyreanitrile