title: Indoor and outdoor concentrations of inorganic acidic aerosols and gases.
abstract: Annular denuder-filter pack sampling systems were used to make indoor and outdoor measurements of aerosol strong H+, SO4(2-), NH4+, NO3- and NO2-, and the gaseous pollutants SO2, HNO3, HONO and NH3 during summer and winter periods in Boston, Massachusetts. Outdoor levels of SO2, HNO3, H+ and SO4(2-) exceeded their indoor concentrations during both seasons. Winter indoor/outdoor ratios were lower than during the summer, probably due to lower air exchange rates during the winter period. During both monitoring periods, indoor/outdoor ratios of aerosol strong H+ were 40-50 percent of the indoor/outdoor SO4(2-) ratio. Since aerosol strong acidity is typically associated with SO4(2-), this finding is indicative of neutralization of the acidic aerosol by the higher indoor NH3 levels. Geometric mean indoor/outdoor NH3 ratios of 3.5 and 23 respectively were measured for the summer and winter sampling periods. For HONO, NH3, NH4+ and NO2-, indoor concentrations were significantly higher than ambient levels. Indoor levels of NO3- were slightly less than outdoor concentrations.
authors.affiliation: Harvard University, School of Public Health, Department of Environmental Health, Boston, Massachusetts.
authors.forename: M
authors.initials: M
authors.lastname: Brauer
authors.forename: P
authors.initials: P
authors.lastname: Koutrakis
authors.forename: G J
authors.initials: GJ
authors.lastname: Keeler
authors.forename: J D
authors.initials: JD
authors.lastname: Spengler
mesh_terms: D000143:Acids / Q000032:analysis*; D000336:Aerosols / Q000032:analysis; D000395:Air Pollutants, Occupational / Q000032:analysis*; D005740:Gases / Q000032:analysis
chemical_list: D000143:Acids; D000336:Aerosols; D000395:Air Pollutants, Occupational; D005740:Gases