title: Crevice corrosion products of dental amalgam.
abstract: The objective of this study was to determine the in vitro corrosion products that resulted from crevice corrosion of low- and high-copper dental amalgams. Specimens were potentiostatically polarized in a chloride-containing electrolyte while set against a PTFE surface to form a crevice. After 16 h, corrosion products were examined by light microscopy, SEM, EDS, and XRD. Analysis showed the presence of three previously reported products [Sn4(OH)6Cl2, SnO, and Cu2O] and a new product, CuCl, which formed on high-copper, gamma 2-free amalgams. Thermodynamic considerations show that CuCl is stable for the reported in vivo potentials of amalgam restorations and the high acidity and high chloride ion concentration associated with crevice corrosion.
authors.affiliation: Division of Dental Biomaterials Science, Faculty of Dentistry, Dalhousie University, Halifax, Nova Scotia, Canada.
authors.forename: E J
authors.initials: EJ
authors.lastname: Sutow
authors.forename: D W
authors.initials: DW
authors.lastname: Jones
authors.forename: G C
authors.initials: GC
authors.lastname: Hall
authors.forename: C G
authors.initials: CG
authors.lastname: Owen
mesh_terms: D003300:Copper / Q000737:chemistry*; D003343:Corrosion; D003723:Dental Amalgam / Q000737:chemistry*; D004356:Drug Storage; D004573:Electrolytes; D004577:Electron Probe Microanalysis; D006868:Hydrolysis; D008422:Materials Testing; D008854:Microscopy, Electron; D013499:Surface Properties; D014001:Tin; D017971:Tin Compounds; D014961:X-Ray Diffraction
chemical_list: D004573:Electrolytes; D017971:Tin Compounds; C023599:stannous chloride; D014001:Tin; D003300:Copper; D003723:Dental Amalgam; C028419:cuprous chloride; C045358:stannic oxide; C029892:cupric chloride