C-C bond formation at the 3'-position of nucleosides by the use of their enol esters.
Nucleosides having an enol ester structure in the sugar portion were synthesized and their reaction with several types of electrophiles were carried out. This furnished a new method for constructing C-C bond at the 3'-position.
Haraguchi
K
K
School of Pharmaceutical Sciences, Showa University, Tokyo, Japan.
Tanaka
H
H
Miyasaka
T
T
D000438:Alcohols / Q000737:chemistry; D002241:Carbohydrates / Q000737:chemistry; D002244:Carbon / Q000737:chemistry*; D004952:Esters / Q000737:chemistry; D015394:Molecular Structure; D009705:Nucleosides / Q000737:chemistry*; D012643:Selenium / Q000737:chemistry
D000438:Alcohols; D002241:Carbohydrates; D004952:Esters; D009705:Nucleosides; D002244:Carbon; D012643:Selenium