Determination of vanadium in water by electrothermal atomisation atomic absorption spectrometry after extraction with 8-hydroxyquinoline in isobutyl methyl ketone.
A sensitive method for the determination of vanadium in water by electrothermal atomisation atomic absorption spectrometry (ETAAS) is described. The vanadium is chelated with 8-hydroxyquinoline in isobutyl methyl ketone and determined by ETAAS after pre-heating the pyrolytic graphite coated graphite tube of a graphite furnace atomiser before injection. The effects of the pH and amount of reagent required for the extraction were studied. The precision, accuracy and interferences of the method were also investigated. The proposed method allows concentrations of vanadium of 0.16 microgram l-1 to be detected.
Bermejo-Barrera
P
P
Analytical Chemistry, Nutrition and Bromatology Department, Faculty of Chemistry, Santiago de Compostela, Spain.
Beceiro-Gonzalez
E
E
Bermejo-Barrera
A
A
Bermejo-Martinez
F
F
D007202:Indicators and Reagents; D008742:Methyl n-Butyl Ketone; D015125:Oxyquinoline; D013054:Spectrophotometry, Atomic; D014639:Vanadium / Q000032:analysis*; D014867:Water / Q000032:analysis*
D007202:Indicators and Reagents; D014639:Vanadium; D014867:Water; D015125:Oxyquinoline; D008742:Methyl n-Butyl Ketone; C005458:methyl isobutyl ketone