The intramolecular migration of a trimethylsilyl group located alpha to a sulfone in substituted cyclohexyl systems.
The intramolecular migration of a trimethylsilyl moiety alpha to a sulfone group of some modified cyclohexyl ring systems is investigated. The large difference in the relative abundance of this rearrangement ion for similar compounds is related to the stability of the protonated species.
Wood
K V
KV
Department of Chemistry, Purdue University, West Lafayette, Indiana 47907.
Rothwell
A P
AP
Anderson
M B
MB
Fuchs
P L
PL
D013058:Mass Spectrometry; D013450:Sulfones / Q000737:chemistry*; D014297:Trimethylsilyl Compounds / Q000737:chemistry*
D013450:Sulfones; D014297:Trimethylsilyl Compounds