Liquid chromatographic determination of acifluorfen in soil and water.
An analytical method based on the use of a liquid chromatograph equipped with a UV detector was developed for the determination of acifluorfen in soil and water. Acifluorfen was extracted from soil in methanol-0.10N NaOH (80 + 20 v/v) and from water by partition with dichloromethane. Solvent partitioning and solid-phase extraction were used to separate acifluorfen from major interfering sample components. Average recoveries from soil at 1, 0.1, and 0.01 ppm fortification levels were 95.1 +/- 3.4, 92.6 +/- 2.9, and 73.9 +/- 3.0%, respectively. Recoveries from water spiked at levels from 0.01 to 1 ppm averaged 96.5 +/- 5.4%. Method limits of detection were 0.006 ppm in soil and 0.003 ppm in water.
Gennari
M
M
University of Turin, Istituto di Chimica Agraria, Italy.
Negre
M
M
Cignetti
A
A
D002853:Chromatography, Liquid; D006540:Herbicides / Q000032:analysis*; D006863:Hydrogen-Ion Concentration; D007202:Indicators and Reagents; D009579:Nitrobenzoates / Q000032:analysis*; D010573:Pesticide Residues / Q000032:analysis; D012987:Soil / Q000032:analysis*; D013056:Spectrophotometry, Ultraviolet; D014867:Water / Q000032:analysis
D006540:Herbicides; D007202:Indicators and Reagents; D009579:Nitrobenzoates; D010573:Pesticide Residues; D012987:Soil; D014867:Water; C018425:acifluorfen