title: Synthesis of 7 alpha,12 alpha-dihydroxy-3 alpha- [2-(beta-D-glucopyranosyl)acetyl]-5 beta-cholan-24-oic acid.
abstract: A C-glucoside of cholic acid was synthesized by the introduction of an acetyl group at position 3 alpha and direct one-pot C-glucosidation using 2,3,4,6-tetra-O-benzyl-alpha-D-glucopyranosyl chloride.
authors.affiliation: Department of Chemistry and Biochemistry, University of Milan, Faculty of Medicine, Italy.
authors.forename: P
authors.initials: P
authors.lastname: Allevi
authors.forename: M
authors.initials: M
authors.lastname: Anastasia
authors.forename: P
authors.initials: P
authors.lastname: Ciuffreda
authors.forename: A
authors.initials: A
authors.lastname: Fiecchi
authors.forename: A M
authors.initials: AM
authors.lastname: Sanvito
mesh_terms: D055598:Chemical Phenomena; D002621:Chemistry; D002793:Cholic Acids / Q000138:chemical synthesis*; D005960:Glucosides / Q000138:chemical synthesis; D015394:Molecular Structure
chemical_list: D002793:Cholic Acids; D005960:Glucosides; C065892:7,12-dihydroxy-3-(2-(glucopyranosyl)acetyl)cholan-24-oic acid; C007036:cholanic acid