title: [Chemical constituents of Armillaria mellea mycelium. VI. Isolation and structure of armillaripin].
abstract: A new protoilludane sesquiterpenoid aromatic ester, named armillaripin, C24H30O6, mp 202-204 degrees C, [alpha]D15 + 130 degrees (c 0.055, CHCl3), was isolated from the petroleum ether extract of the artificially cultured mycelium of Armillaria mellea (Vahl. ex Fr.) Quel. (Tricolometaceae) by silica gel chromatography. On the basis of spectral (UV, IR, 1HNMR 13CNMR and MS) analysis its structure was deduced as I and confirmed by single-crystal X-ray analysis.
authors.affiliation: Institute of Materia Medica, Chinese Academy of Medical Sciences, Beijing.
authors.forename: J S
authors.initials: JS
authors.lastname: Yang
authors.forename: Y L
authors.initials: YL
authors.lastname: Su
authors.forename: Y L
authors.initials: YL
authors.lastname: Wang
authors.forename: X Z
authors.initials: XZ
authors.lastname: Feng
authors.forename: D Q
authors.initials: DQ
authors.lastname: Yu
authors.forename: X T
authors.initials: XT
authors.lastname: Liang
authors.forename: C H
authors.initials: CH
authors.lastname: He
authors.forename: Q T
authors.initials: QT
authors.lastname: Zheng
authors.forename: J J
authors.initials: JJ
authors.lastname: Yang
authors.forename: J
authors.initials: J
authors.lastname: Yang
mesh_terms: D000363:Agaricales / Q000032:analysis*; D055598:Chemical Phenomena; D002621:Chemistry; D008968:Molecular Conformation; D012717:Sesquiterpenes / Q000737:chemistry / Q000302:isolation & purification*
chemical_list: D012717:Sesquiterpenes; C067210:armillaripin