Palladium(II)-coproporphyrin I as a photoactivable group in sequence-specific modification of nucleic acids by oligonucleotide derivatives.
The 34-mer oligodeoxynucleotide was shown to be selectively modified at the G17 position upon photoirradiation in the presence of complementary 17-mer oligodeoxynucleotide bearing Pd(II)-coproporphyrin I covalently linked to the 5'-end phosphate group.
Fedorova
O S
OS
Institute of Bioorganic Chemistry, Siberian Division of the USSR Academy of Sciences, Novosibirsk.
Savitskii
A P
AP
Shoikhet
K G
KG
Ponomarev
G V
GV
D001345:Autoradiography; D001483:Base Sequence; D003306:Coproporphyrins; D008969:Molecular Sequence Data; D009838:Oligodeoxyribonucleotides / Q000138:chemical synthesis; D010165:Palladium; D010761:Phosphorus Radioisotopes; D010777:Photochemistry; D011166:Porphyrins
D003306:Coproporphyrins; D009838:Oligodeoxyribonucleotides; D010761:Phosphorus Radioisotopes; D011166:Porphyrins; C057160:palladium coproporphyrin; D010165:Palladium