Structure of bis(imidazole)(5,10,15,20-tetraphenylporphinato)iron(III) bis(cis-1,2-dicyanoethylenedithiolato)cuprate(III) Tetrakis(tetrahydrofuran) solvate.
[Fe(C44H28N4)(C3H4N2)2][Cu(C4N2S2)2].-4C4H8O, Mr = 1437.1, triclinic, P1-, a = 10.012 (4), b = 11.604 (6), c = 15.802 (7) A, alpha = 71.42 (4), beta = 87.12 (3), gamma = 78.45 (4) degrees, V = 1704 (1) A3, Z = 1, Dx = 1.40 g cm-3, lambda(Mo K alpha) = 0.7107 A, mu = 6.9 cm-1, F(000) = 747, T = 143 K, R = 0.063 for 4935 unique observed reflections. Fe is six-coordinate, Fe--N(porphinato) (av.) = 1.99 (2), Fe--N(imidazole) = 1.981 (3) A; Cu--S (av.) = 2.172 (8) A.
Serr
B R
BR
Department of Chemistry, Colorado State University, Fort Collins 80523.
Headford
C E
CE
Elliott
C M
CM
Anderson
O P
OP
D008665:Metalloporphyrins / Q000032:analysis*; D008968:Molecular Conformation; D009942:Organometallic Compounds; D014961:X-Ray Diffraction
D008665:Metalloporphyrins; D009942:Organometallic Compounds; C064327:bis(imidazole)(5,10,15,20-tetraphenylporphinato)iron(III) bis(1,2-dicyanoethylenedithiolato)cuprate(III) tetrakis(tetrahydrofuran)