Through-bond electron-transfer interaction in proteins.
A model for the through-bond electronic interaction between electron donor and acceptor in proteins is developed. We use a one-electron Hamiltonian, write the Dyson's equation in site representation and solve it by using a Green's function formalism with some renormalization ideas. An expression for Tab which describes the exponential decay with distance bond per bond is obtained. Covalent, non-covalent and convergent pathways are considered and no periodic approximation is needed.
da Gama
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Departamento de Química Fundamental, Universidade Federal de Pernambuco, PE, Brasil.
D000818:Animals; D004583:Electrons; D008954:Models, Biological; D011506:Proteins / Q000502:physiology*
D011506:Proteins