[Helix-coil transitions of a polypeptide in a two-component solvent].
A microscopic model is considered of a helix-coil transition of polypeptides in a two-component solvent one of whose components competes for the formation of hydrogen bonds with the peptide group. It is shown that by a redetermination of the temperature parameter the model is reduced to a polypeptide chain without the solvent. Behavior of the transition parameters is calculated in relation to the solvent concentration competing for the formation of hydrogen bonds at different parameters of polypeptide-solvent interaction.
Kulaga
L L
LL
Morozov
V F
VF
Shakarian
V F
VF
D008433:Mathematics; D008962:Models, Theoretical; D011487:Protein Conformation; D012997:Solvents
D012997:Solvents
Perekhod spiral'-klubok polipeptidov v dvukhkomponentnom rastvoritele.