[The effect of long-range interactions between adsorbed ligands on the DNA helix-coil transition].
The influence of different types of long-range interaction of ligands adsorbed on DNA on the helix-coil transition was theoretically considered. The contact interaction was shown to differ significantly from the long-rang one. It was shown also that even weak dependence of a long-range potential on a degree of helicity resulted in the strong changes of a DNA melting curve. This result allowed to understand the different experimental data on DNA melting in the presence of different substances which reduced AT-and GC-base pairs thermostability difference.
A A
AA
Akhrem
D Iu
DIu
Lando
A G
AG
Shpakovskiĭ
Iu D
IuD
Nechipurenko
S G
SG
Arutiunian
D000327:Adsorption; D004247:DNA; D008024:Ligands; D008962:Models, Theoretical; D009690:Nucleic Acid Conformation
D008024:Ligands; D004247:DNA
Vliianie vzaimodeĭstviia dal'nego poriadka mezhdu adsorbirovannymi ligandami na perekhod spiral'-klubok DNK.