Use of polymeric sorbents for the off-line preconcentration of priority pollutant phenols from water for high-performance liquid chromatographic analysis.
The use of porous polymeric minicolumns for the determination of phenols from the U.S. Environmental Priority Pollutant List was studied. For the off-line preconcentration of priority pollutant phenols from water by solid-phase extraction, minicolumns packed with 1,4-di(methacryloyloxymethyl)naphthalene-divinylbenzene copolymer and Amberlite XAD-4 were used. In order to compare the sorption properties of these polymeric sorbents, the recoveries and breakthrough volumes of phenol, p-nitrophenol, 2,4-dinitrophenol, o-chlorophenol, o-nitrophenol, 2,4-dimethylphenol, 4-chloro-m-cresol, 4,6-dinitro-o-cresol, 2,4-dichlorophenol, 2,4,6-trichlorophenol and pentachlorophenol were studied.
Gawdzik
B
B
Institute of Chemistry, Maria Curie-Skłodowska University, Lublin, Poland.
Gawdzik
J
J
Czerwińska-Bil
U
U
D000179:Acrylates; D002733:Chlorophenols / Q000032:analysis*; D002851:Chromatography, High Pressure Liquid / Q000379:methods*; D008689:Methacrylates; D011108:Polymers; D011137:Polystyrenes; D011145:Polyvinyls; D014753:Vinyl Compounds; D014873:Water Pollutants / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis*
D000179:Acrylates; D002733:Chlorophenols; D008689:Methacrylates; D011108:Polymers; D011137:Polystyrenes; D011145:Polyvinyls; D014753:Vinyl Compounds; D014873:Water Pollutants; D014874:Water Pollutants, Chemical; C012101:XAD-4 resin; C065653:1,4-di-(methacryloyloxymethyl)naphthalene-divinylbenzene copolymer; C004985:divinyl benzene