[Synthesis of cytidine diphosphate-3,6-dideoxyhexoses--donors of glycosyl residues in the biosynthesis of O-specific polysaccharides of Salmonella of serogroups A, B and C].
Interaction of lithium alcoholates of 2,4-di-O-benzoates of paratose and abequose with tetrabenzyl pyrophosphate gave alpha-phosphates of the 3,6-dideoxyhexoses, further converted into the corresponding cytidine-5'-diphosphate derivatives. These synthetic nucleotides were shown to participate in the biosynthesis of the O-specific polysaccharides for Salmonella typhimurium and S. nitra.
Utkina
N S
NS
Danilov
L L
LL
Druzhinina
T N
TN
Shibaev
V N
VN
D000942:Antigens, Bacterial / Q000096:biosynthesis*; D055598:Chemical Phenomena; D002621:Chemistry; D002850:Chromatography, Gel; D006031:Glycosylation; D006601:Hexoses / Q000138:chemical synthesis*; D009682:Magnetic Resonance Spectroscopy; D009702:Nucleoside Diphosphate Sugars / Q000138:chemical synthesis*; D019081:O Antigens; D011135:Polysaccharides, Bacterial / Q000096:biosynthesis*; D012475:Salmonella / Q000276:immunology*
D000942:Antigens, Bacterial; D006601:Hexoses; D009702:Nucleoside Diphosphate Sugars; D019081:O Antigens; D011135:Polysaccharides, Bacterial
Sintez tsitidindifosfat-3,6-didezoksigeksoz--donorov glikozil'nykh ostatkov pri biosinteze O-spetsificheskikh polisakharidov salmonell serogrupp A, B i C.