[Properties of titanium dioxide-polymer composite with titanate coupling agents].
Titanium dioxide-polymethacrylate composites were prepared with triethyleneglycol dimethacrylate (TEGDMA), 1,6-bis(methacryloxy-2-ethoxycarbonylamino)-2,4,4-trimeth  ylexane (UDMA) and rutile structure titanium dioxide. The coupling agents used were isopropyldimethacrylisostearoyl titanate (KR7), isopropyltri (dioctylphosphate) titanate (KR12) and 4-methacryloxyethyl trimellitate anhydride (4-META). Compressive and transverse strengths of composites were determined under various experimental conditions. Compressive strength of composite with KR 7-treated titanium dioxide was higher than that with untreated titanium dioxide. Transverse strength of the composite with 4-META-treated titanium dioxide was higher than that with untreated titanium dioxide. Both compressive and transverse strengths increased when the titanium dioxide was treated with the mixture of KR7 and 4-META. Scanning electron microscopic observations of fractured composite surfaces showed titanium dioxide polymer interface failure with untreated specimens and polymer cohesive fracture with KR7 + 4-META-treated specimens. The results suggest that titanium dioxide treated with both KR7 and 4-META is useful as a pigment of the opaque material of fixed prosthodontic composite.
Yoshida
K
K
Matsumura
H
H
Tanaka
T
T
Atsuta
M
M
D003188:Composite Resins / Q000737:chemistry*; D008689:Methacrylates / Q000737:chemistry; D008855:Microscopy, Electron, Scanning; D010860:Pigments, Biological; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*
D003188:Composite Resins; D008689:Methacrylates; D010860:Pigments, Biological; C009495:titanium dioxide; C034139:4-methacryloxyethyltrimellitic acid anhydride; D014025:Titanium