[Study of the influence of the anodic potential on metal-components dissolution from dental alloys].
This study aims to evaluate the influence of the anodic potential on metal-components dissolution from dental alloys and is intended to serve as an aid in the investigation of dental metal eruption (metal allergy). In the experiments, anodic potentials were applied electrochemically to various dental alloys in a 0.9% NaCl solution. Thereafter amounts of metal-component dissolution were measured by means of atomic absorption spectrophotometry. In addition, relations between metal-component dissolution and electrochemical characteristics (anodic polarization and charge transfer calculated from current density-time transients) were considered.


RESULTS
1. Breakdown potentials determined on the basis of anodic polarization profiles agreed with potentials of remarkable increase in component dissolution. 2. Current density-time transients gave good indications of alloys' corrosion tendencies. Correlations between charge transfer and total amounts of metal-component dissolution were comparatively good. 3. Metal-component dissolutions in various alloys at fixed anodic potentials 1) Cu and Zn were found to dissolve slightly from gold alloys (types II and IV) at potentials above 200 mV (vs SCE). 2) Ag, Pd, Cu, and Zn were found to dissolve from the Ag-Pd-Cu-Au alloy at potentials above 100 mV. A comparatively large amount of Zn was released at low potentials. Amounts of Ag and Cu dissolution increased rapidly at 300 mV and 500 mV respectively. Although traces of it were detectable at low potentials, dissolution of Pd increased remarkably at 500 mV. 3) Ag, In, and Zn were found to dissolve from the Ag-In-Zn alloy at potentials above O mV. Amounts of In and Zn dissolution increased above 20 mV. The increase was especially remarkable in the case of In. 4) Sn and Zn were found to dissolve from the Ag-Sn-Zn alloy at potentials above -200 mV; Ag dissolved from the same alloy at potentials above 100 mV. Amounts of Sn and Zn dissolution increased at potentials above 100 mV. This was especially true in the case of Sn. 5) Ni, Cu and Si were found to dissolve from the soft type Ni-Cr alloy (9.0 wt% Cr) at potentials above -100 mV. Cr, Mn, and Fe dissolved from the same alloy at potentials above 0 mV; and Co at potentials above 200 mV. Metal-component dissolution was greater in the case of this alloy than in those of all the other alloys used in this study. A considerable amount fo Ni was released at 0 mV.(ABSTRACT TRUNCATED AT 400 WORDS)
Kobayashi
H
H
D002858:Chromium Alloys / Q000737:chemistry; D003300:Copper / Q000737:chemistry; D003722:Dental Alloys / Q000009:adverse effects / Q000737:chemistry*; D004563:Electrochemistry; D006801:Humans; D006967:Hypersensitivity / Q000209:etiology; D007204:Indium / Q000737:chemistry; D007501:Iron / Q000737:chemistry; D008345:Manganese / Q000737:chemistry; D008982:Molybdenum / Q000737:chemistry; D009532:Nickel / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D012825:Silicon / Q000737:chemistry; D012834:Silver / Q000737:chemistry; D013054:Spectrophotometry, Atomic; D015032:Zinc / Q000737:chemistry
D002858:Chromium Alloys; D003722:Dental Alloys; D007204:Indium; D012834:Silver; D008345:Manganese; D010165:Palladium; D003300:Copper; D009532:Nickel; D008982:Molybdenum; D007501:Iron; D015032:Zinc; D012825:Silicon