New phospholipid fatty acids from the Caribbean sponge Ectyoplasia ferox.
The phospholipid fatty acids from the Caribbean sponge Ectyoplasia ferox were studied. The novel fatty acids 25-methyl-5,9-heptacosadienoic (1) and 26-methyl-5,9-heptacosadienoic (2) were identified in 3.4 and 2.0% abundance, respectively, representing the longest set of delta 5,9 iso and anteiso acids yet isolated from a marine sponge. The new acid 10,13-dimethyltetradecanoic (3), the unusual acid 15-methyl-11-hexadecenoic (4) and the also novel acid 9-methyl-11-hexadecenoic (5) were also identified in E. ferox. The principal sterols isolated from E. ferox were 24-ethylcholest-5-en-3 beta-ol (46%) and 24(R)-methylcholesta-5,22-dien-3 beta-ol (14%).
Carballeira
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NM
Department of Chemistry, University of Puerto Rico, Rio Piedras 00931.
Maldonado
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ME
D000818:Animals; D003063:Cnidaria / Q000032:analysis*; D005227:Fatty Acids / Q000302:isolation & purification*; D010743:Phospholipids / Q000302:isolation & purification*
D005227:Fatty Acids; D010743:Phospholipids