[A study on the formation of apatite crystallized with gel method].
About apatite produced with a silicahydro gel method using calcium nitrate (group I) or calcium chloride (group II) and a gelatin gel method by use of calcium nitrate (group III) or calcium chloride (group IV), the formative volume as well as the formative condition of a periodic-layered precipitate (Liesegang ring), the pH measurement, calculation of Ca/P ratio, an estimation of the chlorine ion, morphological observation with a scanning electron microscope, qualitative analyses by X-ray diffraction (identification, crystallite size, lattice imperfections, lattice constants) and the composition analysis by infrared absorption spectroscopy were carried out to elucidate the formation of apatite using the gel method. The result showed that there were no distinct differences between group I-II and group III-IV, and it is suggested that it is possible to form satisfact fluorapatite with a gel method using calcium chloride as well as calcium nitrate.
Endo
T
T
Amano
N
N
Yoshida
M
M
Murakami
H
H
Kosuge
N
N
Ohmi
Y
Y
Kameda
A
A
D001031:Apatites / Q000737:chemistry*; D002118:Calcium; D002122:Calcium Chloride; D017610:Calcium Compounds; D003460:Crystallization; D017886:Durapatite; D005461:Fluorine; D005782:Gels; D006882:Hydroxyapatites / Q000737:chemistry; D009566:Nitrates; D014961:X-Ray Diffraction
D001031:Apatites; D017610:Calcium Compounds; D005782:Gels; D006882:Hydroxyapatites; D009566:Nitrates; D005461:Fluorine; D017886:Durapatite; C025105:fluorapatite; D002122:Calcium Chloride; C059948:calcium nitrate; D002118:Calcium