title: Novel synthesis of carbocyclic nucleosides from 2-azabicyclo[2.2.1]heptanes via the reductive N2-C3 cleavage reaction as a key step.
abstract: Carbocyclic ribofuranosyl and arabinofuranosyl pyrimidine nucleosides were synthesized stereoselectively from 2-azabicyclo[2.2.1]hept-5-en-3-one via NaBH4 promoted C-N bond cleavage reaction as a key step.
authors.affiliation: Pharmaceutical Institute, Tohoku University, Sendai, Japan.
authors.forename: N
authors.initials: N
authors.lastname: Katagiri
authors.forename: M
authors.initials: M
authors.lastname: Muto
authors.forename: C
authors.initials: C
authors.lastname: Kaneko
mesh_terms: D001087:Arabinonucleosides / Q000138:chemical synthesis*; D007769:Lactams; D009705:Nucleosides / Q000138:chemical synthesis*
chemical_list: D001087:Arabinonucleosides; D007769:Lactams; D009705:Nucleosides; C062350:2-azabicyclo(2.2.1)hept-5-en-3-one