Structure of ethyl 2-chloro-4-methyl-6-(1-pyrrolidinyl)benzoate.
C14H18ClNO2, Mr = 267.7, orthorhombic, Pbca, a = 10.571 (3), b = 12.081 (5), c = 21.384 (6) A, V = 2731 A3, Z = 8, Dx = 1.30 g cm-3, Mo K alpha, lambda = 0.71069 A, mu = 3.59 cm-1, F(000) = 1136, T = 293 K, R = 0.0357 for 716 observed reflections. In molecules of the title compound the ester substituent is forced from conjugation with the aromatic ring and nitrogen long pair by steric interaction with the adjacent chlorine.
Schlicksupp
L
L
Department of Chemistry, University of Idaho, Moscow 83843.
Quincy
D A
DA
Natale
N R
NR
D055598:Chemical Phenomena; D002627:Chemistry, Physical; D015394:Molecular Structure; D011759:Pyrrolidines; D014961:X-Ray Diffraction
D011759:Pyrrolidines; C062583:ethyl 2-chloro-4-methyl-6-(1-pyrrolidinyl)benzoate