Organoselenium-mediated addition of carbon radicals to 4',5'-unsaturated uracil-nucleosides and its stereocontrol.
Stereocontrolled addition of carbon radicals to 4',5'-unsaturated uracil-nucleosides can be accomplished by using organoselenium reagents as a radical source. This provides a new method for C-C bond formation at the 5'-position.
Haraguchi
K
K
School of Pharmaceutical Sciences, Showa University, Tokyo, Japan.
Tanaka
H
H
Miyasaka
T
T
D007202:Indicators and Reagents; D012643:Selenium; D013237:Stereoisomerism; D014529:Uridine / Q000031:analogs & derivatives* / Q000138:chemical synthesis
D007202:Indicators and Reagents; D012643:Selenium; D014529:Uridine